Skip to Content
MilliporeSigma
All Photos(2)

Key Documents

683108

Sigma-Aldrich

Chiralyst P310

Umicore, 99%

Synonym(s):

(Acetylacetonato)(1,5-cyclooctadiene)rhodium(I), Acetylacetonato(1,5-cyclooctadiene)rhodium(I), Rh(acac)(COD)

Sign Into View Organizational & Contract Pricing


About This Item

Empirical Formula (Hill Notation):
C13H19O2Rh
CAS Number:
Molecular Weight:
310.19
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

Assay

99%

form

solid

reaction suitability

core: rhodium
reaction type: Cross Couplings
reagent type: catalyst

mp

138-140 °C (lit.)

SMILES string

CC(=O)\C=C(\C)O[Rh].C1CC=CCCC=C1

InChI

1S/C8H12.C5H8O2.Rh/c1-2-4-6-8-7-5-3-1;1-4(6)3-5(2)7;/h1-2,7-8H,3-6H2;3,6H,1-2H3;/q;;+1/p-1/b2-1-,8-7-;4-3-;

InChI key

TVGPAHONTUMCNP-DWVXZKBMSA-M

Looking for similar products? Visit Product Comparison Guide

Application

Catalyst/precursor for enantioselective/asymmetric hydrogenations, isomerization/hydroformylations, carbozincation reactions, and silylation of aryl electrophiles

Legal Information

Product of Umicore

Additional information available at www.pmc.umicore.com

related product

Product No.
Description
Pricing

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Benoit Gourdet et al.
Journal of the American Chemical Society, 131(11), 3802-3803 (2009-03-04)
A new rhodium-catalyzed carbozincation of ynamides has been developed, using diorganozinc reagents or functionalized alkylzinc halides. The reactions are highly regio- and stereoselective, allowing access to a wide range of multisubstituted enamides, which are increasingly important building blocks for organic
Yonehara, K.; Hashizume, T. et al.
The Journal of Organic Chemistry, 64, 5598-5598 (1999)
New Phosphorus Ligands for the Rhodium-Catalyzed Isomerization/Hydroformylation of Internal Octenes.
Detlef Selent et al.
Angewandte Chemie (International ed. in English), 40(9), 1696-1698 (2001-05-16)
G Sava et al.
Chemico-biological interactions, 45(1), 1-6 (1983-07-01)
The effects of square planar rhodium, [RhacacCOD]o and iridium, [IracacCOD]o complexes and of octahedral ruthenium, [cis-RuCl2 (DMSO)4]o complex have been examined in comparison with cis-dichlorodiammino platinum(II) (cis-PDD). The toxicity in BDF1 mice varies widely and decreasing LD50-values, ranging from 0.94

Articles

Precatalysts for asymmetric catalysis offer batch-to-batch consistency in a range of catalytic reactions, supporting diverse research needs.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service