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Key Documents

745480

Sigma-Aldrich

Zinc isopropylsulfinate

95%

Synonym(s):

Baran Isopropylation Reagent, Baran IPS Reagent, Bis((isopropylsulfinyl)oxy)zinc, IPS

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About This Item

Empirical Formula (Hill Notation):
C6H14O4S2Zn
CAS Number:
Molecular Weight:
279.69
MDL number:
UNSPSC Code:
12352001
PubChem Substance ID:
NACRES:
NA.22

Assay

95%

form

solid

reaction suitability

reaction type: Allylation
reaction type: C-C Bond Formation
reagent type: catalyst
reaction type: C-H Activation

reagent type: diversification reagent

mp

161-166 °C

SMILES string

CC(C)S(=O)O[Zn]OS(=O)C(C)C

InChI

1S/2C3H8O2S.Zn/c2*1-3(2)6(4)5;/h2*3H,1-2H3,(H,4,5);/q;;+2/p-2

InChI key

PEEMMWYYSHSBTQ-UHFFFAOYSA-L

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Application

Zinc isopropylsulfinate (IPS) is part of a zinc sulfinate toolbox developed by Phil Baran for the simple and rapid diversification of heterocycles.


Practical and Innate Carbon-Hydrogen Functionalization of Heterocycles

Learn More at the Professor and Product Portal of Professor Phil S. Baran.

Linkage

Frequently Asked Questions are available for this Product.

Preparation Note

may contain up to 1 mole eq ZnCl2

Other Notes

Previously sold under product number L511161

Signal Word

Danger

Hazard Statements

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Meiqi Niu et al.
eLife, 9 (2020-07-03)
The intraparietal sulcus (IPS) is structurally and functionally heterogeneous. We performed a quantitative cyto-/myelo- and receptor architectonical analysis to provide a multimodal map of the macaque IPS. We identified 17 cortical areas, including novel areas PEipe, PEipi (external and internal
Jasmine Siew Min Chia et al.
Frontiers in pharmacology, 11, 92-92 (2020-03-21)
Zerumbone has shown great potential in various pathophysiological models of diseases, particularly in neuropathic pain conditions. Further understanding the mechanisms of action is important to develop zerumbone as a potential anti-nociceptive agent. Numerous receptors and pathways function to inhibit and
Thapanee Srichumpong et al.
Dental materials journal, 38(3), 378-387 (2019-03-15)
The mica-based glass-ceramics were prepared in the SiO2-Al2O3-MgO-MgF2-SrCO3-CaCO3-CaF2-P2O5 glass system. There were four mica-based glass-ceramics produced in this study according to the pigment added (CeO2 or Pr-ZrSiO4/Fe-ZrSiO4) and crystallization time (5-35 min). Four dental glass-ceramics, which were leucite-based, lithium disilicate-based
Bonnie Bailet et al.
The Science of the total environment, 745, 140948-140948 (2020-08-01)
Ecological assessment of lakes and rivers using benthic diatom assemblages currently requires considerable taxonomic expertise to identify species using light microscopy. This traditional approach is also time-consuming. Diatom metabarcoding is a promising alternative and there is increasing interest in using
Lucia K Zaugg et al.
Clinical oral implants research, 29(1), 82-90 (2017-10-19)
The purpose of this study was to analyze the cement excess produced when cementing CAD/CAM-fabricated lithium disilicate (L) or zirconium dioxide (Z) crowns using adhesive cement (A) or resin-modified glass ionomer cement (B). Three different cementation techniques were applied: palatal

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