Skip to Content
MilliporeSigma
All Photos(2)

Key Documents

156256

Sigma-Aldrich

Sodium methoxide solution

25 wt. % in methanol

Synonym(s):

Sodium methylate

Sign Into View Organizational & Contract Pricing


About This Item

Linear Formula:
CH3ONa
CAS Number:
Molecular Weight:
54.02
Beilstein:
3592982
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.21

vapor density

1.1 (vs air)

Quality Level

vapor pressure

50 mmHg ( 20 °C)
96 mmHg ( 25 °C)

form

liquid

autoignition temp.

878 °F

concentration

25 wt. % in methanol

refractive index

n20/D 1.37

density

0.945 g/mL at 25 °C

SMILES string

[Na+].C[O-]

InChI

1S/CH3O.Na/c1-2;/h1H3;/q-1;+1

InChI key

WQDUMFSSJAZKTM-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

Related Categories

General description

The product is 25wt.% solution of sodium methoxide in methanol. Its reaction with unactivated aryl bromides in the presence of copper catalyst under various reaction conditions has been studied. It reacts with aryl halides in the presence of a palladium catalyst in DMF (Dimethylformamide) to afford arenes.

Application

A novel high-spin hexanuclear Mn(III) cluster, [NaMn6(OMe)12(dbm)6]+, was synthesized via MnCl2 oxidation with simultaneous NaOMe promoted aggregation. This cluster has an unprecedented cyclic structure and 24 unpaired electrons in its ground state.
Sodium methoxide solution has been used in the synthesis of NO-containing nanoparticles (SNO-NP).

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - Skin Corr. 1A - STOT SE 1

Target Organs

Eyes,Central nervous system

Supplementary Hazards

Storage Class Code

3 - Flammable liquids

WGK

WGK 2

Flash Point(F)

60.0 °F - closed cup - Solvent

Flash Point(C)

15.55 °C - closed cup - Solvent


Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Customers Also Viewed

Brian J Riley et al.
ACS applied materials & interfaces, 12(17), 19682-19692 (2020-04-16)
In this paper, sodium aluminosilicate aerogels and xerogels were evaluated as scaffolds for a variety of different getters including Ag+, Cs+, Cu2+, Fe3+, K+, Li+, Rb+, Sb3+, Sn2+, and Sn4+ for the capture of gaseous iodine coming from nuclear facilities.
Jessica Beekman et al.
Food additives & contaminants. Part A, Chemistry, analysis, control, exposure & risk assessment, 37(1), 48-60 (2019-10-10)
Fatty acid esters of 3-monochloropropanediol (3-MCPD), 2-monochlorpropanediol (2-MCPD), and glycidol are process-induced chemical contaminants found in refined vegetable oils. Due to their toxicological properties, there is potential concern regarding exposure to these compounds, particularly for formula-fed infants where refined edible
Palladium hydrides in organic synthesis. Reduction of aryl halides by sodium methoxide catalyzed by tetrakis (triphenylphosphine) palladium.
Zask A and Helquist P.
The Journal of Organic Chemistry, 43(8), 1619-1620 (1978)
Sonu Kumar et al.
Macromolecular bioscience, 20(6), e2000048-e2000048 (2020-04-15)
The synthesis and self-assembly of peptide-polymer conjugates into fibrillar nanostructures are reported, based on the amyloidogenic peptide KLVFF. A strategy for rational synthesis of polymer-peptide conjugates is documented via tethering of the amyloidogenic peptide segment LVFF (Aβ17-20 ) and its
Alex Schudel et al.
Nature nanotechnology, 15(6), 491-499 (2020-06-12)
Therapeutic delivery selectively to lymph nodes has the potential to address a variety of unmet clinical needs. However, owing to the unique structure of the lymphatics and the size-restrictive nature of the lymph node reticular network, delivering cargo to specific

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service