- New one-pot synthesis of (E)-beta-aryl vinyl halides from styrenes.
New one-pot synthesis of (E)-beta-aryl vinyl halides from styrenes.
Organic letters (2009-07-04)
Piotr Pawluć, Grzegorz Hreczycho, Justyna Szudkowska, Maciej Kubicki, Bogdan Marciniec
PMID19572730
ABSTRACT
A new, efficient protocol for the highly stereoselective one-pot synthesis of (E)-beta-aryl vinyl iodides and (E)-beta-aryl vinyl bromides from styrenes based on sequential ruthenium-catalyzed silylative coupling-N-halosuccinimide-mediated halodesilylation reactions is reported.
MATERIALS