sp3-sp3 Coupling reactions in the synthesis of natural products and biologically active molecules.

sp3-sp3 Coupling reactions in the synthesis of natural products and biologically active molecules.

Natural product reports (2014-02-28)

Egor Geist, Andreas Kirschning, Thomas Schmidt

ABSTRACT

This Highlight covers the current status of relatively unexplored sp(3)-sp(3) cross-coupling reactions with particular focus on natural product and related syntheses.

MATERIALS

Product Number

Brand

Product Description

357634

Sigma-Aldrich

Nickel, wire, diam. 0.25 mm, ≥99.9%

510068

Sigma-Aldrich

Raney^®-Nickel, W.R. Grace and Co. Raney^® 3202, slurry, in H₂O, active catalyst

203904

Sigma-Aldrich

Nickel, powder, <150 μm, 99.99% trace metals basis

221678

Sigma-Aldrich

Raney^®-Nickel, W.R. Grace and Co. Raney^® 2800, slurry, in H₂O, active catalyst

268259

Sigma-Aldrich

Nickel, foil, thickness 0.125 mm, ≥99.9%

268283

Sigma-Aldrich

Nickel, powder, <1 μm, 99.8% trace metals basis

267007

Sigma-Aldrich

Nickel, foil, thickness 0.25 mm, 99.995% trace metals basis

267058

Sigma-Aldrich

Nickel, wire, diam. 0.5 mm, ≥99.99% trace metals basis

510033

Sigma-Aldrich

Raney^®-Nickel, W.R. Grace and Co. Raney^® 2400, slurry, in H₂O, active catalyst

GF32263354

Nickel, foil, 25x25mm, thickness 0.25mm, as rolled, 99.99+%

GF26283179

Nickel, foil, 0.5m coil, thickness 0.3mm, annealed, 99%

GF47006243

Nickel, foil, 10mm disks, thickness 0.025mm, as rolled, 100%

GF58446580

Nickel, foil, 10m coil, thickness 0.3mm, coil width 1mm, as rolled, 99%

GF91050140

Nickel, wire reel, 100m, diameter 0.125mm, hard, 99.98%

GF26387534

Nickel, foil, 0.5m coil, thickness 0.003mm, 99.95%

GF72359017

Nickel, foil, 50x50mm, thickness 0.25mm, as rolled, 99.999%

GF64268118

Nickel, foil, 4mm disks, thickness 0.05mm, 99.9%

GF00494883

Nickel, foil, 10m coil, thickness 0.20mm, coil width 1mm, annealed, 99%

GF34426470

Nickel, tube, 500mm, outside diameter 5.9mm, inside diameter 5.65mm, wall thickness 0.125mm, hard, 99.5%

GF36794829

Nickel, foil, 50x50mm, thickness 0.25mm, annealed, 99.98%

GF84616207

Nickel, foil, 10mm disks, thickness 0.008mm, 99.95%

GF19063380

Nickel, foil, 150x150mm, thickness 0.3mm, as rolled, 99.999%

GF86067210

Nickel, wire reel, 100m, diameter 1.0mm, as drawn, 99%

GF81996014

Nickel, pellets, 100g, max. size 10mm, 99.99+%

GF65888274

Nickel, foil, 0.5m coil, thickness 0.30mm, as rolled, 99.98%

GF95098731

Nickel, foil, 2m coil, thickness 0.3mm, coil width 1mm, annealed, 99%

GF70540556

Nickel, tube, 500mm, outside diameter 4.5mm, inside diameter 3.154mm, wall thickness 0.673mm, hard, 99.5%

GF65651564

Nickel, foil, 10m coil, thickness 0.3mm, coil width 1mm, annealed, 99%

GF87610776

Nickel, foil, 50x50mm, thickness 0.125mm, annealed, 99.98%

GF70648915

Nickel, foil, 2m coil, thickness 0.1mm, annealed, 99%