sp3-sp3 Coupling reactions in the synthesis of natural products and biologically active molecules.

sp3-sp3 Coupling reactions in the synthesis of natural products and biologically active molecules.

Natural product reports (2014-02-28)

Egor Geist, Andreas Kirschning, Thomas Schmidt

ABSTRACT

This Highlight covers the current status of relatively unexplored sp(3)-sp(3) cross-coupling reactions with particular focus on natural product and related syntheses.

MATERIALS

Product Number

Brand

Product Description

577995

Sigma-Aldrich

Nickel, nanopowder, <100 nm avg. part. size, ≥99% trace metals basis

267074

Sigma-Aldrich

Nickel, rod, diam. 6.35 mm, ≥99.99% trace metals basis

357553

Sigma-Aldrich

Nickel, foil, thickness 0.5 mm, 99.98% trace metals basis

357626

Sigma-Aldrich

Nickel, wire, diam. 0.5 mm, ≥99.9% trace metals basis

357588

Sigma-Aldrich

Nickel, foil, thickness 0.1 mm, 99.98% trace metals basis

266981

Sigma-Aldrich

Nickel, powder, <50 μm, 99.7% trace metals basis

GF70332870

Nickel, rod, 100mm, diameter 3.3mm, 99.99+%

GF82156912

Nickel, rod, 100mm, diameter 12.0mm, 99%

GF99799968

Nickel, rod, 100mm, diameter 30mm, 99%

GF83416798

Nickel, wire reel, 10m, diameter 0.01mm, as drawn, 99.98%

GF96533758

Nickel, rod, 100mm, diameter 10.0mm, 99.99+%

GF85861042

Nickel, foil, 0.5m coil, thickness 0.125mm, annealed, 99%

GF84515687

Nickel, tube, 500mm, outside diameter 1.8mm, inside diameter 1.6mm, wall thickness 0.1mm, hard, 99.5%

GF88557519

Nickel, wire reel, 100m, diameter 0.25mm, hard, 99.98%

GF97256953

Nickel, wire reel, 1m, diameter 0.25mm, as drawn, 99.99+%

GF72690778

Nickel, foil, 150x150mm, thickness 1.0mm, annealed, 99%

GF91748953

Nickel, wire reel, 0.2m, diameter 0.5mm, as drawn, 99.99+%

GF95071103

Nickel, tube, 500mm, outside diameter 2.8mm, inside diameter 1.8mm, wall thickness 0.5mm, hard, 99.5%

GF69929274

Nickel, rod, 1000mm, diameter 3.0mm, 99%

GF88624132

Nickel, foil, 2m coil, thickness 0.075mm, as rolled, 99.98%

GF91581239

Nickel, tube, 500mm, outside diameter 1.5mm, inside diameter 1.4mm, wall thickness 0.05mm, hard, 99.5%

GF82377816

Nickel, foil, 50x50mm, thickness 0.125mm, as rolled, 99.999%

GF69666328

Nickel, rod, 1000mm, diameter 6.35mm, 99%

GF98112977

Nickel, wire reel, 100m, diameter 0.125mm, as drawn, 99%

GF73152233

Nickel, foil, 0.5m coil, thickness 0.15mm, annealed, 99%

GF74649695

Nickel, foil, 2m coil, thickness 0.3mm, annealed, 99%

GF68100454

Nickel, wire reel, 10m, diameter 0.125mm, annealed, 99.98%

GF90435887

Nickel, foil, 0.5m coil, thickness 0.20mm, annealed, 99%

GF98554078

Nickel, tube, 500mm, outside diameter 3.25mm, inside diameter 3.05mm, wall thickness 0.1mm, hard, 99.5%

GF67355624

Nickel, foil, 0.5m coil, thickness 0.025mm, 99.9%