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Key Documents

32222-M

Sigma-Aldrich

Dichloromethane

puriss. p.a., ACS reagent, reag. ISO, ≥99.9% (GC)

Synonym(s):

methylene chloride, Methylene chloride

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About This Item

Empirical Formula (Hill Notation):
CH2Cl2
CAS Number:
Molecular Weight:
84.93
Beilstein:
1730800
EC Number:
MDL number:
UNSPSC Code:
12352101
PubChem Substance ID:
NACRES:
NA.21

grade

ACS reagent
puriss. p.a.

Quality Level

Agency

reag. ISO

vapor density

2.9 (vs air)

vapor pressure

24.45 psi ( 55 °C)
6.83 psi ( 20 °C)

Assay

≥99.9% (GC)

form

liquid

autoignition temp.

1223 °F

contains

10-60 ppm amylene as stabilizer

expl. lim.

22 %

impurities

≤0.00002% free chlorine (Cl)
≤0.0005% formaldehyde
≤0.001% free acid (as HCl)
≤0.001% non-volatile matter
≤0.01% chloroform (GC)
≤0.01% tetrachloromethane (GC)
≤0.01% water (Karl Fischer)
≤0.05% ethanol (GC)

refractive index

n20/D 1.4235-1.4245
n20/D 1.424 (lit.)

bp

39.8-40 °C (lit.)

mp

−95 °C (lit.)

density

1.320-1.330 g/L at 20 °C
1.325 g/mL at 25 °C (lit.)

anion traces

chloride (Cl-): ≤0.5 mg/kg

cation traces

Al: ≤0.5 mg/kg
B: ≤0.02 mg/kg
Ba: ≤0.1 mg/kg
Bi: ≤0.10 ppm
Ca: ≤0.5 mg/kg
Cd: ≤0.05 mg/kg
Co: ≤0.02 mg/kg
Cr: ≤0.02 mg/kg
Cu: ≤0.02 mg/kg
Fe: ≤0.1 mg/kg
K: ≤0.50 ppm
Li: ≤0.10 ppm
Mg: ≤0.1 mg/kg
Mn: ≤0.02 mg/kg
Mo: ≤0.10 ppm
Na: ≤0.50 ppm
Ni: ≤0.02 mg/kg
Pb: ≤0.1 mg/kg
Sn: ≤0.1 mg/kg
Sr: ≤0.1 ppm
Zn: ≤0.1 mg/kg

SMILES string

ClCCl

suitability

passes test for reaction against H2SO4

InChI

1S/CH2Cl2/c2-1-3/h1H2

InChI key

YMWUJEATGCHHMB-UHFFFAOYSA-N

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General description

Dichloromethane has been tested as a solvent medium for dipyridine-chromium(VI) oxide. Solubility was reported to be 12.5g/100ml. The apparent adsorption constant of the TiO2 loaded activated carbon for dichloromethane was found to be inversely proportional to the quantity of loaded TiO2.

Application

Dichloromethane may be used as a solvent for the preparation of stock solutions of carotenoids. It may be employed as a solvent in the synthesis of polylactide-based (PLA) thin films.

Pictograms

Health hazardExclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Central nervous system

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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R Re et al.
Free radical biology & medicine, 26(9-10), 1231-1237 (1999-06-25)
A method for the screening of antioxidant activity is reported as a decolorization assay applicable to both lipophilic and hydrophilic antioxidants, including flavonoids, hydroxycinnamates, carotenoids, and plasma antioxidants. The pre-formed radical monocation of 2,2'-azinobis-(3-ethylbenzothiazoline-6-sulfonic acid) (ABTS*+) is generated by oxidation
V Melissinaki et al.
Biofabrication, 3(4), 045005-045005 (2011-09-21)
This study reports on the production of high-resolution 3D structures of polylactide-based materials via multi-photon polymerization and explores their use as neural tissue engineering scaffolds. To achieve this, a liquid polylactide resin was synthesized in house and rendered photocurable via

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