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160997

Sigma-Aldrich

5,10,15,20-Tetraphenyl-21H,23H-porphine

97%

Synonym(s):

meso-Tetraphenylporphyrin, TPP

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About This Item

Empirical Formula (Hill Notation):
C44H30N4
CAS Number:
917-23-7
Molecular Weight:
614.74
Beilstein:
379542
EC Number:
213-025-9
MDL number:
MFCD00011680
UNSPSC Code:
12171500
PubChem Substance ID:
24849899
NACRES:
NA.47

Quality Level

100

Assay

97%

form

powder or crystals

impurities

1-3% corresponding chlorin

mp

>300 °C (lit.)

solubility

chloroform: 1 mg/mL, clear to opaque

λmax

514 nm

ε (extinction coefficient)

≥3500 at 480-486 nm in toluene
≥4000 at 647-653 nm in toluene
≥5000 at 589-595  nm in toluene
≥8000 at 546-552 nm in toluene

application(s)

diagnostic assay manufacturing
hematology
histology

storage temp.

room temp

SMILES string

c1ccc(cc1)-c2c3ccc(n3)c(-c4ccccc4)c5ccc([nH]5)c(-c6ccccc6)c7ccc(n7)c(-c8ccccc8)c9ccc2[nH]9

InChI

1S/C44H30N4/c1-5-13-29(14-6-1)41-33-21-23-35(45-33)42(30-15-7-2-8-16-30)37-25-27-39(47-37)44(32-19-11-4-12-20-32)40-28-26-38(48-40)43(31-17-9-3-10-18-31)36-24-22-34(41)46-36/h1-28,45,48H/b41-33-,41-34-,42-35-,42-37-,43-36-,43-38-,44-39-,44-40-

InChI key

YNHJECZULSZAQK-LWQDQPMZSA-N

Gene Information

human ... TERT(7015)

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General description

5,10,15,20-Tetraphenyl-21H,23H-porphine is a porphyrin compound.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
SHBR5475
MKCF4142
MKBP7614V
MKBC6522
25396TH

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Zerrin Sezgin et al.
International journal of pharmaceutics, 332(1-2), 161-167 (2006-10-24)
Meso-tetraphenyl porphine (mTPP) is a highly lipophilic, fluorescent porphyrin derivate and it is used as photosensitizer on the treatment of malign neoplasms. The aim of this study was to prepare mTPP loaded pluronic F127 and polyethylene glycol-distearoyl phosphatidylethanolamine (PEG(2000)-DSPE) micelles
Maria Bassiouk et al.
Journal of nanoscience and nanotechnology, 11(6), 5457-5468 (2011-07-21)
The self-assembly of porphyrins into highly organized functional arrays supported on appropriate solid substrates is an area of research with multiple potential applications in the "bottom-up" approach to manufacturing. In order to analyze the self-assembly of meso-tetraphenylporphine (H2TPP) on the
Anette Weyergang et al.
Biochimica et biophysica acta, 1830(3), 2659-2670 (2013-05-15)
Tyrosin kinase inhibitors (TKIs) and monoclonal antibodies aimed to target epidermal growth factor receptor (EGFR) have shown limited effect as monotherapies and drug resistance is a major limitation for therapeutic success. Adjuvant therapies to EGFR targeting therapeutics are therefore of
Satoshi Tsukahara et al.
Analytical and bioanalytical chemistry, 395(4), 1047-1053 (2009-07-09)
Rhombic-ordered microdomains of diprotonated 5,10,15,20-tetraphenylporphine aggregate, whose sizes were 10-200 microm, were formed at dodecane/aqueous H(2)SO(4) interfaces. The light excitation of their two absorption bands (410 and 473 nm for H- and J-bands, respectively) led to one fluorescence band at
Zachary J Tonzetich et al.
Inorganic chemistry, 50(4), 1570-1579 (2011-01-20)
Several nitrosyl complexes of Fe and Co have been prepared using the sterically hindered Ar-nacnac ligand (Ar-nacnac = anion of [(2,6-diisopropylphenyl)NC(Me)](2)CH). The dinitrosyliron complexes [Fe(NO)(2)(Ar-nacnac)] (1) and (Bu(4)N)[Fe(NO)(2)(Ar-nacnac)] (2) react with [Fe(III)(TPP)Cl] (TPP = tetraphenylporphine dianion) to generate [Fe(II)(NO)(TPP)] and
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