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Sigma-Aldrich

(3-Mercaptopropyl)trimethoxysilane

95%

Synonym(s):

3-(Trimethoxysilyl)-1-propanethiol

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About This Item

Linear Formula:
HS(CH2)3Si(OCH3)3
CAS Number:
Molecular Weight:
196.34
Beilstein:
2038119
EC Number:
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.23

Assay

95%

form

liquid

refractive index

n20/D 1.444 (lit.)

bp

213-215 °C (lit.)

density

1.057 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

CO[Si](CCCS)(OC)OC

InChI

1S/C6H16O3SSi/c1-7-11(8-2,9-3)6-4-5-10/h10H,4-6H2,1-3H3

InChI key

UUEWCQRISZBELL-UHFFFAOYSA-N

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General description

(3-Mercaptopropyl) trimethoxysilane (MPS) is predominantly used as a precursor for silica.
(3-mercaptopropyl)trimethoxysilane (MPTMS) is an organosilane with a thiol group, which can be used as a self-assembled monolayer (SAM). It can be used as a conjunction reagent to immobilize a variety of nanoparticles.

Application

MPTMS can be coated with TiO2, CeO2 and La2O3 for protection against corrosion on quaternary bronze in urban atmosphere. It can also be used as a silica nanofluid (NF) to modify the surface of berea sandstone to improve the enhanced oil recovery (EOR) area in the petroleum industry. MPTMS forms composites with kaolin, that can be used as an absorbent for the removal of heavy metals from wastewater. MPTMS can form a bilayer with multiwalled carbon nanotubes (MWNTs) on gold electrodes which can be used to study the electrochemical properties of fluphenazine.

Pictograms

Exclamation markEnvironment

Signal Word

Warning

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2 - Skin Sens. 1

Storage Class Code

10 - Combustible liquids

WGK

WGK 2

Flash Point(F)

204.8 °F - closed cup

Flash Point(C)

96 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Hydrolysis and condensation of self-assembled monolayers of (3-mercaptopropyl) trimethoxysilane on Ag and Au surfaces."
Thompson WR, et al.
Langmuir, 13(8), 2291-2302 (1997)
Jie Wang et al.
Nanoscale, 9(40), 15598-15605 (2017-10-11)
Promoted therapeutic angiogenesis is a major objective in the area of regenerative medicine, and sufficient vascularization of artificial tissues or organs is one of the main difficulties for the realization of tissue engineering methods. The identification of new kinds of
XPS and electrochemical evaluation of two-dimensional organic films obtained by chemical modification of self-assembled monolayers of (3-mercaptopropyl) trimethoxysilane on copper surfaces.
Sinapi F, et al.
Materials Science & Engineering. C, Materials For Biological Applications, 22(2), 345-353 (2002)
Response surface approach for optimization of Hg (II) adsorption by 3-mercaptopropyl trimethoxysilane-modified kaolin minerals from aqueous solution.
Yilmaz S et al.
Korean Journal of Chemical Engineering, 34(8), 2225-2235 (2017)
P Knittel et al.
Faraday discussions, 193, 353-369 (2016-10-07)
The characterization of nanoparticles and the correlation of physical properties such as size and shape to their (electro)chemical properties is an emerging field, which may facilitate future optimization and tuning of devices involving nanoparticles. This requires the investigation of individual

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