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338761

Sigma-Aldrich

Triphenylphosphine-d15

≥98 atom % D, 99% (CP)

Synonym(s):

Tris(pentadeuterophenyl)phosphine, Tri(phenyl-d5)phosphine

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About This Item

Linear Formula:
(C6D5)3P
CAS Number:
24762-44-5
Molecular Weight:
277.38
MDL number:
MFCD00075150
UNSPSC Code:
12352128
PubChem Substance ID:
24860572
NACRES:
NA.12

isotopic purity

≥98 atom % D

Assay

99% (CP)

form

powder

bp

377 °C

mp

79-81 °C (lit.)

mass shift

M+15

SMILES string

[2H]c1c([2H])c([2H])c(c([2H])c1[2H])P(c2c([2H])c([2H])c([2H])c([2H])c2[2H])c3c([2H])c([2H])c([2H])c([2H])c3[2H]

InChI

1S/C18H15P/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H/i1D,2D,3D,4D,5D,6D,7D,8D,9D,10D,11D,12D,13D,14D,15D

InChI key

RIOQSEWOXXDEQQ-KLHTYYPYSA-N

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Application

Employed in a mechanistic study of cis-bis(silylmethyl)platinum(II) complexes.

Packaging

This product may be available from bulk stock and can be packaged on demand. For information on pricing, availability and packaging, please contact Stable Isotopes Customer Service.

Signal Word

Danger

Hazard Statements

H302,H317,H318,H372

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Sens. 1B - STOT RE 1 Inhalation

Target Organs

Central nervous system,Peripheral nervous system

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 2

Flash Point(F)

428.0 °F - closed cup

Flash Point(C)

220.00 °C - closed cup

Certificates of Analysis (COA)

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Journal of the American Chemical Society, 116, 9963-9963 (1994)
Elliot L Bennett et al.
Inorganic chemistry, 53(6), 2963-2967 (2014-02-28)
A structural, spectroscopic, and computational investigation of Stryker's reagent, [HCu{P(C6H5)3}]6, and its isotopomers has provided new insights into the complex. Neutron diffraction shows that the hydrides are best described as edge bridging rather than face bridging. The combination of infrared
Elliot Bennett et al.
Inorganic chemistry, 54(5), 2213-2220 (2015-02-12)
CuH is a material that appears in a wide diversity of circumstances ranging from catalysis to electrochemistry to organic synthesis. There are both aqueous and nonaqueous synthetic routes to CuH, each of which apparently leads to a different product. We

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