sp3-sp3 Coupling reactions in the synthesis of natural products and biologically active molecules.

sp3-sp3 Coupling reactions in the synthesis of natural products and biologically active molecules.

Natural product reports (2014-02-28)

Egor Geist, Andreas Kirschning, Thomas Schmidt

ABSTRACT

This Highlight covers the current status of relatively unexplored sp(3)-sp(3) cross-coupling reactions with particular focus on natural product and related syntheses.

MATERIALS

Product Number

Brand

Product Description

357588

Sigma-Aldrich

Nickel, foil, thickness 0.1 mm, 99.98% trace metals basis

266981

Sigma-Aldrich

Nickel, powder, <50 μm, 99.7% trace metals basis

577995

Sigma-Aldrich

Nickel, nanopowder, <100 nm avg. part. size, ≥99% trace metals basis

357553

Sigma-Aldrich

Nickel, foil, thickness 0.5 mm, 99.98% trace metals basis

267074

Sigma-Aldrich

Nickel, rod, diam. 6.35 mm, ≥99.99% trace metals basis

357626

Sigma-Aldrich

Nickel, wire, diam. 0.5 mm, ≥99.9% trace metals basis

GF04942414

Nickel, wire reel, 5m, diameter 0.5mm, hard, 99.98%

GF25257573

Nickel, wire reel, 50m, diameter 0.25mm, annealed, 99%

GF17568861

Nickel, tube, 1000mm, outside diameter 4.5mm, inside diameter 3.154mm, wall thickness 0.673mm, hard, 99.5%

GF59535557

Nickel, foil, 1m coil, thickness 0.3mm, coil width 1mm, annealed, 99%

GF38105388

Nickel, tube, 200mm, outside diameter 7.11mm, inside diameter 6.57mm, wall thickness 0.27mm, hard, 99.5%

GF37232489

Nickel, tube, 1000mm, outside diameter 0.65mm, inside diameter 0.384mm, wall thickness 0.133mm, as drawn, 99.5%

GF57702348

Nickel, wire reel, 500m, diameter 0.25mm, hard, 99.98%

GF66250256

Nickel, rod, 200mm, diameter 10.0mm, 99.99+%

GF49925896

Nickel, foil, 1m coil, thickness 0.075mm, as rolled, 99.98%

GF38194386

Nickel, rod, 50mm, diameter 10.0mm, 99.99+%

GF61615739

Nickel, wire reel, 1m, diameter 1.0mm, as drawn, 99%

GF17365192

Nickel, foil, 1m coil, thickness 0.1mm, annealed, 99%

GF07926037

Nickel, rod, 50mm, diameter 40mm, 99%

GF25364325

Nickel, tube, 200mm, outside diameter 4.5mm, inside diameter 3.154mm, wall thickness 0.673mm, hard, 99.5%

GF01728738

Nickel, rod, 500mm, diameter 12.0mm, 99%

GF10605967

Nickel, foil, 1m coil, thickness 0.3mm, coil width 1mm, as rolled, 99%

GF36638118

Nickel, foil, 1m coil, thickness 0.0075mm, 99.95%

GF49774034

Nickel, rod, 200mm, diameter 12.7mm, 99.98%

GF17767468

Nickel, foil, not light tested, 25x25mm, thickness 0.00075mm, temporary acrylic support, 99.95%

GF57913285

Nickel, tube, 100mm, outside diameter 2.8mm, inside diameter 1.8mm, wall thickness 0.5mm, hard, 99.5%

GF04485944

Nickel, foil, 1m coil, thickness 0.20mm, annealed, 99%

GF44280974

Nickel, rod, 200mm, diameter 40mm, 99%

GF44869731

Nickel, wire reel, 20m, diameter 0.025mm, as drawn, 99.98%

GF13442879

Nickel, tube, 200mm, outside diameter 5.5mm, inside diameter 5mm, wall thickness 0.25mm, hard, 99.5%