Skip to Content
Merck
All Photos(2)

Key Documents

934038

Sigma-Aldrich

Hexafluoroisopropyl methyl ether

greener alternative

≥99%, anhydrous, battery grade

Synonym(s):

1,1,1,3,3,3-Hexafluoro-2-methoxypropane, HFME, HFPM, Isoindoklon

Sign Into View Organizational & Contract Pricing


About This Item

Empirical Formula (Hill Notation):
C4H4F6O
CAS Number:
Molecular Weight:
182.06
Enzyme Commission number:
603-501-8
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.21

grade

battery grade

Quality Level

description

Application: Battery manufacturing

Assay

≥99%

form

liquid

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

impurities

≤250 ppm acid (HF)
≤500 ppm H2O

bp

50 °C

density

1.39 g/mL

application(s)

battery manufacturing

greener alternative category

General description

Hexafluoroisopropyl methyl ether (HFPM) is a fluorinated ether, also called isoflurothyl in biomedical applications as a general anesthetic. HFPM is a colorless, non-flammable liquid used in the battery industry as a high-performing cosolvent and additive for electrolyte formulations in lithium-ion batteries. HFPM has a low viscosity and a low boiling point and is miscible with many polar organic solvents, which lend it use as a diluent for low-temperature applications. Our battery-grade HFPM is an important component in the production of safe and efficient lithium-ion batteries for use in a wide range of applications.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Click here for more information.

Application

Battery-grade hexafluoroisopropyl methyl ether (HFPM) is a versatile and highly effective cosolvent and electrolyte additive for use in lithium-ion batteries (LiBs) and sodium-ion batteries (SIBs). With its low viscosity, low boiling point, and compatibility with a variety of battery solvents, HFPM is an ideal diluent for low-temperature applications and can help to improve the wettability of polypropylene separators. Additionally, HFPM′s nonflammability is a major benefit for battery safety. HFPM also has good compatibility with most electrode materials including for example, lithium metal, graphite, NMCs, and LMO. Studies have shown that in SIBs adding HFPM as an electrolyte additive can help to stabilize the Na electrode surface and form a new fluorine-containing organic layer, resulting in a more stable solid electrolyte interphase. Overall, battery-grade HFPM is a crucial component in the production of high-performing, reliable, and safe lithium-ion batteries for a wide range of applications, from consumer electronics to electric vehicles.

Storage Class Code

10 - Combustible liquids

WGK

WGK 3


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Regulated interfacial stability by coordinating ionic liquids with fluorinated solvent for high voltage and safety batteries
Yan, et al.
Journal of Power Sources, 491, 229603-229603 (2021)
5?V-Class Electrolytes Based on Fluorinated Solvents for Li-Ion Batteries with Excellent Cyclability
Xia, L., et al.
ChemElectroChem, 2, 1707? 1712-1707? 1712 (2015)
Qiang Yi et al.
ACS applied materials & interfaces, 11(50), 46965-46972 (2019-11-20)
Sodium-metal batteries with conventional organic liquid electrolytes have disadvantages including dendrite deposition and safety concern. In this work, we report a low-flammable electrolyte (NaPF6-FRE) consisting of 1 M NaPF6 in 1,2-dimethoxyethane (DME), fluoroethylene carbonate (FEC), and 1,1,1,3,3,3-hexafluoroisopropylmethyl ether (HFPM) (2:1:2

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service