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Merck

Silver-mediated fluorination of aryl silanes.

Tetrahedron (2011-06-22)
Pingping Tang, Tobias Ritter
ABSTRACT

A regiospecific silver-mediated fluorination of aryl silanes is reported. The reaction is operationally simple, and employs Ag(2)O as readily available, inexpensive silver source, which can be recovered.

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1-Fluoro-3-nitrobenzene, 97%
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Bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate
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