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Key Documents

131652

Sigma-Aldrich

Pyridine N-oxide

95%

동의어(들):

Pyridine oxide

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About This Item

실험식(Hill 표기법):
C5H5NO
CAS Number:
Molecular Weight:
95.10
Beilstein:
105257
EC Number:
MDL number:
UNSPSC 코드:
12352100
PubChem Substance ID:
NACRES:
NA.22

분석

95%

형태

solid

bp

270 °C (lit.)

mp

62-67 °C (lit.)

SMILES string

[O-][n+]1ccccc1

InChI

1S/C5H5NO/c7-6-4-2-1-3-5-6/h1-5H

InChI key

ILVXOBCQQYKLDS-UHFFFAOYSA-N

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일반 설명

Pyridine N-oxide axle with [2]rotaxanes was synthesized via an anion templated threading-followed-by-stoppering strategy.

애플리케이션

Pyridine N-oxide was used to study the FTIR spectra of pyridine N-oxide in acetonitrile.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

289.4 °F - closed cup

Flash Point (°C)

143 °C - closed cup

개인 보호 장비

dust mask type N95 (US), Eyeshields, Gloves


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문서 라이브러리 방문

Masahito Murai et al.
Chemical communications (Cambridge, England), 48(61), 7622-7624 (2012-06-26)
Gold(I)-catalysed tandem oxygen-transfer/cycloisomerisation reaction of 2-(2-propynyl)pyridine N-oxides provides an atom-economical route to indolizinone frameworks.
Xue Gong et al.
Organic letters, 13(7), 1766-1769 (2011-03-11)
A Pd(II)-catalyzed oxidative coupling between pyridine N-oxides and N-substituted indoles via 2-fold C-H bond activation was achieved with high selectivity using Ag(2)CO(3) as an oxidant.
Jinshui Chen et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 15(30), 7268-7276 (2009-07-07)
Optically active chiral alkyl chlorides are valuable compounds because of their bioactivity and versatile synthetic utility. Accordingly, the ring opening of epoxides with a chloride nucleophile stands as an important goal in asymmetric catalysis. We describe herein recent advances in
Santiago Barroso et al.
Organic letters, 13(3), 402-405 (2010-12-24)
Enantioselective nitrone cycloadditions with 2-alkenoyl pyridine N-oxides as dipolarophiles have been reported. The reaction is catalyzed by Cu(II)-BOX complexes to give the expected isoxazolidine products with high diastereo- and enantioselectivity.
Munawar Hussain et al.
Organic letters, 15(1), 54-57 (2012-12-22)
The synthesis of optically active piperidines by enantioselective addition of aryl Grignard reagents to pyridine N-oxides and lithium binolate followed by reduction is reported for the first time. The reaction results in high yields (51-94%) in combination with good ee

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