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Key Documents

175889

Sigma-Aldrich

tert-Butanol-d10

99 atom % D

동의어(들):

2-Methyl-2-propanol-d10, tert-Butyl alcohol-d10

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About This Item

Linear Formula:
(CD3)3COD
CAS Number:
Molecular Weight:
84.18
EC Number:
MDL number:
UNSPSC 코드:
12142201
PubChem Substance ID:
NACRES:
NA.21

동위원소 순도

99 atom % D

분석

99% (CP)

형태

liquid

기술

NMR: suitable

불순물

≤0.5% water
water

refractive index

n20/D 1.3835 (lit.)

bp

82 °C (lit.)

density

0.893 g/mL at 25 °C (lit.)

질량 이동

M+10

SMILES string

[2H]OC(C([2H])([2H])[2H])(C([2H])([2H])[2H])C([2H])([2H])[2H]

InChI

1S/C4H10O/c1-4(2,3)5/h5H,1-3H3/i1D3,2D3,3D3,5D

InChI key

DKGAVHZHDRPRBM-SGLLWXCUSA-N

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일반 설명

tert-Butanol-d10 (tert-Butyl alcohol-d10) is a deuterated derivative of tert-butanol. It participates in the synthesis of cyanoacetic acid-tert-butylester-d9. Conformational analysis of 2,3-dihydroxypropanoic acid in tert-butyl alcohol-d10 indicates the dominance of gauche-hydroxyl rotamers (92%) under low pH conditions.

애플리케이션

tert-Butanol-d10 may be used in the synthesis of cyanoacetic acid-tert-butylester-d9 and tert-butoxide-d9 (BuOK-d9).

추천 제품

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픽토그램

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신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

표적 기관

Central nervous system, Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 1

Flash Point (°F)

51.8 °F - closed cup

Flash Point (°C)

11 °C - closed cup


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문서 라이브러리에서 최근에 구매한 제품에 대한 문서를 찾아보세요.

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Silacyclobutane as ?Carbanion Pump? in Anionic Polymerization. III. Synthesis of Di-and Tri-block Copolymer by ?Diphenylsilacyclobutane-Potassium tert-Butoxide System
Hyun J-Y and Kawakami Y
Polymer Journal, 36(10), 856-865 (2004)
Thorsten W Jaskolla et al.
Journal of the American Society for Mass Spectrometry, 22(6), 976-988 (2011-09-29)
This work experimentally verifies and proves the two long since postulated matrix-assisted laser desorption/ionization (MALDI) analyte protonation pathways known as the Lucky Survivor and the gas phase protonation model. Experimental differentiation between the predicted mechanisms becomes possible by the use
Michael D Drake et al.
Magnetic resonance in chemistry : MRC, 44(3), 210-219 (2006-02-16)
Vicinal (1)H--(1)H coupling constants were used to determine the conformational preferences of 2,3-dihydroxypropanoic acid (1) (DL-glyceric acid) in various solvents and its different carboxyl ionization states. The stereospecific assignments of J(12) and J(13) were confirmed through the point-group substitution of

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