추천 제품
![1,8-Diazabicyclo[5.4.0]undec-7-ene 98%](/deepweb/assets/sigmaaldrich/product/structures/120/564/5b373e23-1624-489c-8efb-692de0f96ffb/640/5b373e23-1624-489c-8efb-692de0f96ffb.png)
분석
98%
형태
liquid
refractive index
n20/D 1.436 (lit.)
bp
160-161 °C/730 mmHg (lit.)
density
0.962 g/mL at 25 °C (lit.)
SMILES string
CCOC(=O)C#CC
InChI
1S/C6H8O2/c1-3-5-6(7)8-4-2/h4H2,1-2H3
InChI key
FCJJZKCJURDYNF-UHFFFAOYSA-N
유사한 제품을 찾으십니까? 방문 제품 비교 안내
일반 설명
Ethyl 2-butynoate, a 2-alkynoate is a methanogenesis inhibitor. It is an electron deficient internal alkyne that has been reported to undergo codimerization with alkenes to form 1,3-dienes catalyzed by rhodium(I)/H8-BINAP complex. The annulation of thioamides with ethyl 2-butynoate catalyzed by tri-n-butylphosphine to form thiazolines has been investigated.
애플리케이션
Ethyl 2-butynoate was used in the study of its effect on in vitro degradation and microbial biomass production.
It may be used in the synthesis of the following:
It may be used in the synthesis of the following:
- 3-ethyl, 1-methyl 1-(2-nitrophenyl)-cyclopent-3-ene-1,3-dicarboxylate
- tricyclic aziridine derivatives
- alkenylsilanols
신호어
Warning
유해 및 위험 성명서
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
표적 기관
Respiratory system
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point (°F)
143.6 °F - closed cup
Flash Point (°C)
62 °C - closed cup
개인 보호 장비
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
시험 성적서(COA)
제품의 로트/배치 번호를 입력하여 시험 성적서(COA)을 검색하십시오. 로트 및 배치 번호는 제품 라벨에 있는 ‘로트’ 또는 ‘배치’라는 용어 뒤에서 찾을 수 있습니다.
이미 열람한 고객
Synthesis of 2-azaspiro [4.4] nonan-1-ones via phosphine-catalysed [3+ 2]-cycloadditions.
Yong SR, et al.
Tetrahedron, 61(34), 8120-8129 (2005)
Bing Liu et al.
The Journal of organic chemistry, 67(13), 4595-4598 (2002-06-22)
The annulation of thioamides with 2-alkynoates and 2,3-dienoates under the catalysis of tri-n-butylphosphine was described. The annulation reaction provided a new entry to thiazolines, particularly those with 2-aryl substituents.
Yu Shibata et al.
Organic letters, 10(13), 2829-2831 (2008-06-12)
A cationic rhodium(I)/H(8)-BINAP complex catalyzes codimerization of alkenes bearing no alpha-hydrogen and electron-deficient internal alkynes, leading to 1,3-dienes in good yields with moderate to excellent regio- and stereoselectivity. The same complex also catalyzes codimerization of an acrylate and phenyl-substituted electron-rich
Efficient and stereoselective cross-coupling with highly substituted alkenylsilanols.
Denmark SE and Pan W.
Journal of Organometallic Chemistry, 653(1), 98-104 (2002)
Dichloro [TADDOLato (2-)-O,O'] titanium/Dichlorobis [1-methylethoxy] titanium-Mediated, Highly Diastereo-and Enantioselective Additions of Silyl Enol Ethers to Nitro Olefins and [3+ 2] Cycloadditions of Primary Adducts to Acetylenes.
Seebach D, et al.
Helvetica Chimica Acta, 82(11), 1829-1842 (1999)
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