52985

cis-3-Hexene

≥95.0%

• 실험식(Hill 표기법): C₆H₁₂
• CAS Number: 7642-09-3
• Molecular Weight: 84.16
• Beilstein: 1718858
• MDL number: MFCD00085300
• UNSPSC 코드: 12352100
• PubChem Substance ID: 57651395
• NACRES: NA.22

속성

• 분석: ≥95.0%
• refractive index: n20/D 1.395
• bp: 66-68 °C (lit.)
• density: 0.681 g/mL at 20 °C (lit.)
• SMILES string: CC\C=C/CC
• InChI: 1S/C6H12/c1-3-5-6-4-2/h5-6H,3-4H2,1-2H3/b6-5-
• InChI key: ZQDPJFUHLCOCRG-WAYWQWQTSA-N

설명

일반 설명

cis-3-Hexene is a symmetrical cis-disubstituted alkene that can be prepared by the hydroboration of 3-hexyne followed by protonolysis. The gas-phase study of its molecular structure by electron diffraction combined with molecular mechanical calculations reveals the presence of the (+ac, +ac) and the (-ac, +ac) forms. cis-3-Hexene undergoes epoxidation with dimethyldioxirane to form the corresponding epoxide.

애플리케이션

cis-3-Hexene may be used in the preparation of 3-hexanol via asymmetric hydroboration with diisopinocampheylborane (Ipc₂BH).

안전성 정보

• 픽토그램: GHS02,GHS08,GHS07
• 신호어: Danger
• 유해 및 위험 성명서: H225,H304,H319
• 예방조치 성명서: P210 - P233 - P240 - P301 + P310 - P305 + P351 + P338 - P331
• Hazard Classifications: Asp. Tox. 1 - Eye Irrit. 2 - Flam. Liq. 2
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 3
• Flash Point (°F): -13.0 °F - closed cup
• Flash Point (°C): -25 °C - closed cup
• 개인 보호 장비: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter