747769

[Ir(dtbbpy)(ppy)₂]PF₆

• 동의어(들): [Ir(dtbbpy)(ppy)₂][PF₆], Ir Photocatalyst, [4,4′-Bis(1,1-dimethylethyl)-2,2′-bipyridine-N1,N1′]bis[2-(2-pyridinyl-N)phenyl-C]iridium(III) hexafluorophosphate
• 실험식(Hill 표기법): C₄₀H₄₀F₆IrN₄P
• CAS Number: 676525-77-2
• Molecular Weight: 913.95
• UNSPSC 코드: 12161600
• NACRES: NA.22

속성

• 형태: powder
• Quality Level: 100
• 반응 적합성: core: iridium; reaction type: Photocatalysis; reagent type: catalyst
• 광촉매 활성화: 455 nm
• 저장 온도: 2-8°C
• SMILES string: CC(C1=CC=[N]([Ir]2([N]3=CC=C(C=C34)C(C)(C)C)([N]5=CC=CC=C5C6=CC=CC=C62)(C7=CC=CC=C78)[N]9=C8C=CC=C9)C4=C1)(C)C.FP(F)(F)(F)(F)F
• InChI: 1S/C18H24N2.2C11H8N.F6P.Ir/c1-17(2,3)13-7-9-19-15(11-13)16-12-14(8-10-20-16)18(4,5)6;2*1-2-6-10(7-3-1)11-8-4-5-9-12-11;1-7(2,3,4,5)6;/h7-12H,1-6H3;2*1-6,8-9H;;
• InChI key: DZARMRZNOUWGQE-UHFFFAOYSA-N

설명

애플리케이션

[Ir(dtbbpy)(ppy)₂]PF₆ is an iridium-based photocatalyst which is used to drive various photochemical reactions such as:

• Coupling of N-arylamines and nitroalkanes via an oxidative aza-Henry reaction.
• Atom transfer radical addition (ATRA) of haloalkanes to alkenes and alkynes.
• Conversion of 2-bromoanilides to the corresponding 3,3-disubstituted oxindoles.
• Aryl-alkyl C−C reductive cross-coupling reactions.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

안전성 정보

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable