760838

Allyl tetraisopropylphosphorodiamidite

95%

• Linear Formula: [[(CH₃)₂CH]₂N]₂POCH₂CH=CH₂
• CAS Number: 108554-72-9
• Molecular Weight: 288.41
• MDL number: MFCD00191714
• UNSPSC 코드: 12352302
• PubChem Substance ID: 329766898
• NACRES: NA.22

속성

• 분석: 95%
• 형태: liquid
• refractive index: n20/D 1.466 (lit.); n20/D 1.467
• bp: 114-117 °C/0.4 mmHg (lit.)
• density: 0.903 g/mL at 25 °C (lit.); 0.910 g/mL at 25 °C
• 저장 온도: 2-8°C
• SMILES string: CC(C)N(C(C)C)P(OCC=C)N(C(C)C)C(C)C
• InChI: 1S/C15H33N2OP/c1-10-11-18-19(16(12(2)3)13(4)5)17(14(6)7)15(8)9/h10,12-15H,1,11H2,2-9H3
• InChI key: ZTEGHJIXOZLSOH-UHFFFAOYSA-N

설명

애플리케이션

Allyl tetraisopropylphosphorodiamidite may be used in the total synthesis of (−)-tetrahydrolipstatin, dolabelide C, (-)-salicylihalamides A and B.

Phosphitylation agent used in the preparation of oligonucleotides. Selective deallylation is accomplished by palladium catalysis.

안전성 정보

• 픽토그램: GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H315,H319,H335
• 예방조치 성명서: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 표적 기관: Respiratory system
• Storage Class Code: 10 - Combustible liquids
• WGK: WGK 3
• Flash Point (°F): 188.0 °F
• Flash Point (°C): 86.67 °C