923443

PhMPhos

• 동의어(들): 1-Diadamantylphosphino-1′-diphenylphosphinoferrocene
• 실험식(Hill 표기법): C₄₂H₄₈FeP₂
• Molecular Weight: 670.62
• UNSPSC 코드: 12352200
• NACRES: NA.21

속성

• 형태: powder
• Quality Level: 100
• 반응 적합성: reagent type: catalyst; reaction type: Cross Couplings; reagent type: ligand
• 작용기: phosphine

설명

애플리케이션

PhMPhos is an unsymmetrical ferrocene-based phosphine ligand. The MPhos series of ligands are unsymmetrical diphosphino-ferrocenes bearing a bulky adamantyl group. Pd catalysts containing PhMPhos can be used for a variety of cross-coupling transformations, including Suzuki coupling, C-P coupling, and Csp²-Csp³ coupling. Demonstrated Csp²-Csp³ couplings include Murahashi-Feringa Coupling (Alkyl-Li), Kumada-Corriu coupling (Alkyl-MgX), Negishi coupling (Alkyl-ZnX) and Suzuki–Miyaura coupling (Alkyl-B(OR₂)).

Learn more about MPhos ligands and catalysts

기타 정보

Tunable Unsymmetrical Ferrocene Ligands Bearing a Bulky Di-1-adamantylphosphino Motif for Many Kinds of Csp²–Csp³ Couplings

안전성 정보

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable