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24310

Supelco

α-DEX 120

L × I.D. 30 m × 0.25 mm, df 0.25 μm

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About This Item

EC Number:
UNSPSC 코드:
41115710

material

fused silica

설명

GC capillary column

파라미터

30-230 °C temperature

베타 값

250

df

0.25 μm

기술

gas chromatography (GC): suitable

길이 × I.D.

30 m × 0.25 mm

기질 활성군

non-bonded; 20% permethylated α-cyclodextrin in SPB-35 poly(35% diphenyl/65% dimethylsiloxane) phase

응용 분야

agriculture
chemicals and industrial polymers
cleaning products
clinical
cosmetics
environmental
flavors and fragrances
food and beverages
forensics and toxicology
life science and biopharma
personal care
pharmaceutical (small molecule)

컬럼 유형

capillary chiral

분리 기술

chiral

일반 설명

Capillary GC column is also known as open tubular column. The carrier gas flows through the central aperture and is unrestricted throughout the length of the column.
Containing permethylated α-cyclodextrin embedded in an intermediate polarity stationary phase, Supelco α-DEX 120 columns provide unique selectivity for enantiomeric separations of small molecules. They are also recommended for separating positional isomers (phenols, xylenes, etc.).

애플리케이션

α-DEX 120 was used in a GC column, in an experiment conducted to study the addition of catalytic enantioselective diethylzinc to a-substituted aldehyde, in presence of enantiopure ligand. It was also used to pack chiral column durin GC analysis, in an experiment to investigate lipase-mediated desymmetrization of glycerol with aliphatic and aromatic anhydrides.

화학적/생리학적 저항성

Temp. Limits:
  • 30 °C to 230 °C

기타 정보

We offer a variety of chromatography accessories including analytical syringes

법적 정보

DEX is a trademark of Sigma-Aldrich Co. LLC

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Lipase-mediated desymmetrization of glycerol with aromatic and aliphatic anhydrides.
Batovska D
Tetrahedron Asymmetry, 15 (22), 3551-3559 (2004)
A superior, readily available enantiopure ligand for the catalytic enantioselective addition of diethylzinc to a-substituted aldehydes.
Lluis S
The Journal of Organic Chemistry, 63 (20), 7078-7082 (1998)
Scott RPW.
Introduction to Analytical Gas Chromatography, 101-102 (1997)

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