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15449

Sigma-Aldrich

Boc-His(Trt)-OH

≥98.0% (TLC)

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Synonym(s):
Nα-Boc-N(im)-trityl-L-histidine
Empirical Formula (Hill Notation):
C30H31N3O4
CAS Number:
Molecular Weight:
497.58
Beilstein/REAXYS Number:
732035
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

≥98.0% (TLC)

form

powder

optical activity

[α]20/D +12.5±1.0°, c = 1% in methanol

reaction suitability

reaction type: Boc solid-phase peptide synthesis

mp

~130 °C (dec.)

application(s)

peptide synthesis

SMILES string

CC(C)(C)OC(=O)N[C@@H](Cc1cn(cn1)C(c2ccccc2)(c3ccccc3)c4ccccc4)C(O)=O

InChI

1S/C30H31N3O4/c1-29(2,3)37-28(36)32-26(27(34)35)19-25-20-33(21-31-25)30(22-13-7-4-8-14-22,23-15-9-5-10-16-23)24-17-11-6-12-18-24/h4-18,20-21,26H,19H2,1-3H3,(H,32,36)(H,34,35)/t26-/m0/s1

InChI key

OYXZPXVCRAAKCM-SANMLTNESA-N

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Boc-His(Trt)-OH ≥98.0% (TLC)

15449

Boc-His(Trt)-OH

Boc-D-His-OH ≥98.0% (TLC)

15119

Boc-D-His-OH

Boc-His-OH 99%

408433

Boc-His-OH

Fmoc-D-His(Trt)-OH 97% (HPLC)

772046

Fmoc-D-His(Trt)-OH

assay

≥98.0% (TLC)

assay

≥98.0% (TLC)

assay

99%

assay

97% (HPLC)

mp

~130 °C (dec.)

mp

-

mp

195 °C (dec.) (lit.)

mp

141-146 °C

optical activity

[α]20/D +12.5±1.0°, c = 1% in methanol

optical activity

-

optical activity

[α]20/D +26°, c = 1 in methanol

optical activity

[α]22/D -85.0°, c = 1% in chloroform

reaction suitability

reaction type: Boc solid-phase peptide synthesis

reaction suitability

reaction type: Boc solid-phase peptide synthesis

reaction suitability

reaction type: Boc solid-phase peptide synthesis

reaction suitability

reaction type: Fmoc solid-phase peptide synthesis

application(s)

peptide synthesis

application(s)

peptide synthesis

application(s)

peptide synthesis

application(s)

peptide synthesis

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


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Biomacromolecules, 19(9), 3840-3852 (2018-08-11)
A novel, multifunctional hydrogel that exhibits a unique set of properties for the effective treatment of pancreatic cancer (PC) is presented. The material is composed of a pentablock terpolypeptide of the type PLys- b-(PHIS- co-PBLG)-PLys- b-(PHIS- co-PBLG)- b-PLys, which is
Ngoc-Duc Doan et al.
Journal of peptide science : an official publication of the European Peptide Society, 21(5), 387-391 (2014-11-18)
The solid-phase synthesis of azapeptides possessing a C-terminal aza-residue has been accomplished by a protocol featuring regioselective alkylation of benzhydrylidene-aza-glycinamide and illustrated by the syntheses of [aza-Lys(6)] growth-hormone-releasing peptide-6 analogs.

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