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About This Item
Linear Formula:
BrC6H4CH2OH
CAS Number:
Molecular Weight:
187.03
Beilstein/REAXYS Number:
1931620
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
assay
99%
form
solid
mp
75-77 °C (lit.)
solubility
dioxane: soluble 1 g/10 mL, clear to faintly turbid, colorless to faintly yellow
functional group
bromo
hydroxyl
SMILES string
OCc1ccc(Br)cc1
InChI
1S/C7H7BrO/c8-7-3-1-6(5-9)2-4-7/h1-4,9H,5H2
InChI key
VEDDBHYQWFOITD-UHFFFAOYSA-N
Gene Information
human ... ALOX12(239), ALOX15(246)
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General description
4-Bromobenzyl alcohol undergoes three-component reaction with acetylferrocene and arylboronic acid to give ferrocenyl ketones containing biaryls. It undergoes oxidation reaction in the presence of polyvinylpolypyrrolidone-supported hydrogen peroxide, silica sulfuric acid and ammonium bromide to yield 4-bromobenzaldehyde. It undergoes efficient trimethylsilylation reaction with 1,1,1,3,3,3-hexamethyldisilazane in the presence of catalytic amount of aspartic acid in acetonitrile.
Application
4-Bromobenzyl alcohol was used in the synthesis of:
- hydroxyl end functionalized, substituted polyfluorene
- amphiphilic, symmetric rod-coil, triblock copolymer of poly(9,9-didodecylfluorene-2,7-diyl) and poly(hydroxyl ethyl methacrylate)
hcodes
pcodes
Hazard Classifications
Aquatic Chronic 3
Storage Class
13 - Non Combustible Solids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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