195707

cis-1,4-Dichloro-2-butene

95%

• Synonym(s): (2Z)-1,4-Dichloro-2-butene, (2Z)-1,4-Dichlorobut-2-ene, (Z)-1,4-Dichloro-2-butene, 1,4-Dichloro-cis-2-butene, cis-1,2-Bis(chloromethyl)ethene
• Linear Formula: ClCH₂CH=CHCH₂Cl
• CAS Number: 1476-11-5
• Molecular Weight: 125.00
• Beilstein/REAXYS Number: 1719692
• EC Number: 216-021-5
• MDL number: MFCD00062950
• UNSPSC Code: 12352100
• PubChem Substance ID: 24851705
• NACRES: NA.22

Properties

• assay: 95%
• form: liquid
• refractive index: n20/D 1.489 (lit.)
• bp: 152 °C/758 mmHg (lit.)
• mp: −48 °C (lit.)
• density: 1.188 g/mL at 25 °C (lit.)
• storage temp.: 2-8°C
• SMILES string: ClC\C=C/CCl
• InChI: 1S/C4H6Cl2/c5-3-1-2-4-6/h1-2H,3-4H2/b2-1-
• Inchi Key: FQDIANVAWVHZIR-UPHRSURJSA-N

Description

General description

cis-1,4-Dichloro-2-butene on reaction with sodium amide yields trans-1-chloro-1,3-butadiene. Mechanism of condensation of sulfone-activated methylene compounds with cis-1,4-dichloro-2-butene to yield cyclopentene has been investigated.

Application

cis-1,4-Dichloro-2-butene was used in the preparation of functionalized 3,5-disubstituted cyclopent-2-enones.

Safety Information

• Pictograms: GHS02,GHS06,GHS08,GHS05,GHS09
• signalword: Danger
• hcodes: H226,H301 + H311,H314,H330,H335,H350,H410
• pcodes: P210 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 3 - Flammable liquids
• wgk_germany: WGK 3
• flash_point_f: 131.0 °F - closed cup
• flash_point_c: 55 °C - closed cup
• ppe: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter