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238139

Sigma-Aldrich

1-Iodonaphthalene

97%

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Synonym(s):
1-Naphthyl iodide
Empirical Formula (Hill Notation):
C10H7I
CAS Number:
Molecular Weight:
254.07
Beilstein/REAXYS Number:
1906415
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

97%

refractive index

n20/D 1.701 (lit.)

bp

163-165 °C/15 mmHg (lit.)

density

1.74 g/mL at 25 °C (lit.)

SMILES string

Ic1cccc2ccccc12

InChI

1S/C10H7I/c11-10-7-3-5-8-4-1-2-6-9(8)10/h1-7H

InChI key

NHPPIJMARIVBGU-UHFFFAOYSA-N

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This Item
238260301086179817
1-Iodonaphthalene 97%

238139

1-Iodonaphthalene

1-Iodododecane 98%

238260

1-Iodododecane

1-Iodo-2,2-dimethylpropane 98%

301086

1-Iodo-2,2-dimethylpropane

2-Phenyl-1-propanol 97%

179817

2-Phenyl-1-propanol

Quality Level

200

Quality Level

100

Quality Level

-

Quality Level

100

bp

163-165 °C/15 mmHg (lit.)

bp

159-160 °C/15 mmHg (lit.)

bp

70-71 °C/100 mmHg (lit.)

bp

110-111 °C/10 mmHg (lit.)

density

1.74 g/mL at 25 °C (lit.)

density

1.201 g/mL at 25 °C (lit.)

density

1.494 g/mL at 25 °C (lit.)

density

0.975 g/mL at 25 °C (lit.)

refractive index

n20/D 1.701 (lit.)

refractive index

n20/D 1.484 (lit.)

refractive index

n20/D 1.489 (lit.)

refractive index

n20/D 1.526 (lit.)

General description

Ultrafast relaxation of 1-iodonaphthalene has been studied by time-resolved femtosecond pump-probe mass spectrometry. 1-Iodonaphthalene undergoes Pd catalyzed cross-coupling reaction (Stille reaction) with 2,4-dimethoxy-6-(trimethylstannyl)pyrimidine to afford 2,4-dimethoxy-6-(naphthalen-1-yl)pyrimidine.

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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Raul Montero et al.
Physical chemistry chemical physics : PCCP, 12(28), 7988-7993 (2010-06-03)
The ultrafast relaxation of 1-iodonaphthalene, with particular attention to the dissociation channels, has been studied by time-resolved femtosecond pump-probe mass spectrometry following excitation at 267 and 317 nm. The measured transients for the parent ion and the isobaric fragments, iodine
Javier I Bardagí et al.
The Journal of organic chemistry, 73(12), 4491-4495 (2008-05-21)
From the commercial 6-chloro-2,4-dimethoxypyrimidine (1) and by a photostimulated reaction with Me(3)Sn(-) ions, 2,4-dimethoxy-6-(trimethylstannyl)pyrimidine (2) was obtained in 95% yield. By the cross-coupling reaction of 2 with 1-iodonaphthalene as electrophile catalyzed by Pd (Stille reaction), 2,4-dimethoxy-6-(naphthalen-1-yl)pyrimidine (9) was obtained in

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