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249904

Sigma-Aldrich

3,3-Dimethylallyl bromide

technical grade, ~90%

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Synonym(s):
1-Bromo-3-methyl-2-butene, Prenyl bromide
Linear Formula:
(CH3)2C=CHCH2Br
CAS Number:
Molecular Weight:
149.03
Beilstein/REAXYS Number:
1420778
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22

grade

technical grade

Quality Level

assay

~90%

form

liquid

contains

silver wool as stabilizer

refractive index

n20/D 1.489 (lit.)

bp

82-83 °C/150 mmHg (lit.)

density

1.29 g/mL at 20 °C (lit.)

storage temp.

2-8°C

SMILES string

C\C(C)=C\CBr

InChI

1S/C5H9Br/c1-5(2)3-4-6/h3H,4H2,1-2H3

InChI key

LOYZVRIHVZEDMW-UHFFFAOYSA-N

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This Item
27437289483728276
3,3-Dimethylallyl bromide technical grade, ~90%

249904

3,3-Dimethylallyl bromide

3,3-Dimethylallyl bromide 95%, contains silver wool as stabilizer

274372

3,3-Dimethylallyl bromide

1-Ethyl-3-methylimidazolium bromide ≥97.0% (T)

89483

1-Ethyl-3-methylimidazolium bromide

(Bromoethynyl)benzene ≥95.0% (HPLC)

728276

(Bromoethynyl)benzene

form

liquid

form

-

form

crystals

form

liquid

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

-

storage temp.

−20°C

bp

82-83 °C/150 mmHg (lit.)

bp

82-83 °C/150 mmHg (lit.)

bp

-

bp

-

density

1.29 g/mL at 20 °C (lit.)

density

1.29 g/mL at 20 °C (lit.)

density

-

density

-

refractive index

n20/D 1.489 (lit.)

refractive index

n20/D 1.489 (lit.)

refractive index

-

refractive index

-

Application

3,3-Dimethylallyl bromide has been used in the preparation of:
  • (±)-eldanolide
  • 1-(3,3-dimethylallyl)-L-tryptophan
  • (±)-fumagillin, antibiotic isolated from Aspergillus fumigattus

signalword

Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

104.0 °F - closed cup

flash_point_c

40 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Customers Also Viewed

A direct synthesis of (?)-eldanolide via the highly regioselective prenylation of 2-trimethylsiloxyfuran.
Jefford CW, et al.
Tetrahedron Letters, 28(9), 949-950 (1987)
Biosynthesis of aromatic isoprenoids. Part 5. The preparation of 1-(3, 3-dimethylallyl)-L-tryptophan and cyclo-L-aianyl-1-(3, 3-dimethylallyl)-L-tryptophan and their non-incorporation into echinulin.
Grundon MF, et al.
Journal of the Chemical Society. Perkin Transactions 1, 1294-1298 (1980)
A total synthesis of ( )-fumagillin.
E J Corey et al.
Journal of the American Chemical Society, 94(7), 2549-2550 (1972-04-05)

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