MilliporeSigma
All Photos(1)

281042

Sigma-Aldrich

Tetradecafluorohexane

99%

Sign Into View Organizational & Contract Pricing

Select a Size

Synonym(s):
Perfluorohexane
Linear Formula:
CF3(CF2)4CF3
CAS Number:
Molecular Weight:
338.04
Beilstein:
1802113
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Assay

99%

form

liquid

refractive index

n20/D 1.252 (lit.)

bp

58-60 °C (lit.)

mp

-74 °C (lit.)

density

1.669 g/mL at 25 °C (lit.)

SMILES string

FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F

InChI

1S/C6F14/c7-1(8,3(11,12)5(15,16)17)2(9,10)4(13,14)6(18,19)20

InChI key

ZJIJAJXFLBMLCK-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

Compare Similar Items

View Full Comparison

Show Differences

1 of 4

This Item
334707196649326720
Tetradecafluorohexane 99%

Sigma-Aldrich

281042

Tetradecafluorohexane

2-Fluorobenzonitrile 98%

Sigma-Aldrich

196649

2-Fluorobenzonitrile

Hexafluorobenzene ≥99.5%, NMR grade

Sigma-Aldrich

326720

Hexafluorobenzene

form

liquid

form

-

form

liquid

form

liquid

refractive index

n20/D 1.252 (lit.)

refractive index

-

refractive index

n20/D 1.505 (lit.)

refractive index

n20/D 1.377 (lit.)

bp

58-60 °C (lit.)

bp

-

bp

90 °C/21 mmHg (lit.)

bp

80-82 °C (lit.)

mp

-74 °C (lit.)

mp

49-50 °C (lit.)

mp

-

mp

3.7-4.1 °C (lit.)

density

1.669 g/mL at 25 °C (lit.)

density

-

density

1.116 g/mL at 25 °C (lit.)

density

1.612 g/mL at 25 °C (lit.)

General description

Tetradecafluorohexane in the gas phase reacts spontaneously with lithium amalgam, to give a solid and intimate mixture of lithium fluoride and elemental polymeric carbon with a small amount of superstoichiometric lithium.

Application

Tetradecafluorohexane has been used:
  • as a fluorocarbon organic solvent in the preparation of temperature-induced phase-separation solution
  • to investigate boiling heat transfer mechanisms
  • as a photosensitizer in fluorous biphasic singlet oxygenation
  • as a novel reaction medium for photooxidation reactions

accessory

Product No.
Description
Pricing

Hazard Statements

Precautionary Statements

Hazard Classifications

Aquatic Chronic 3

Storage Class Code

12 - Non Combustible Liquids

WGK

WGK 2

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Documents related to the products that you have purchased in the past have been gathered in the Document Library for your convenience.

Visit the Document Library

Difficulty Finding Your Product Or Lot/Batch Number?

Product numbers are combined with Pack Sizes/Quantity when displayed on the website (example: T1503-25G). Please make sure you enter ONLY the product number in the Product Number field (example: T1503).

Example:

T1503
Product Number
-
25G
Pack Size/Quantity

Additional examples:

705578-5MG-PW

PL860-CGA/SHF-1EA

MMYOMAG-74K-13

1000309185

enter as 1.000309185)

Having trouble? Feel free to contact Technical Service for assistance.

Lot and Batch Numbers can be found on a product's label following the words 'Lot' or 'Batch'.

Aldrich Products

  • For a lot number such as TO09019TO, enter it as 09019TO (without the first two letters 'TO').

  • For a lot number with a filling-code such as 05427ES-021, enter it as 05427ES (without the filling-code '-021').

  • For a lot number with a filling-code such as STBB0728K9, enter it as STBB0728 without the filling-code 'K9'.

Not Finding What You Are Looking For?

In some cases, a COA may not be available online. If your search was unable to find the COA you can request one.

Request COA

Journal of the American Chemical Society, 118, 5312-5312 (1996)
Journal of Heat Transfer, 118, 429-429 (1996)
Michael P Grubb et al.
Nature chemistry, 8(11), 1042-1046 (2016-10-22)
Spectroscopically observing the translational and rotational motion of solute molecules in liquid solutions is typically impeded by their interactions with the solvent, which conceal spectral detail through linewidth broadening. Here we show that unique insights into solute dynamics can be
Synthetic Communications, 26, 1861-1861 (1996)
Koichi Kitaguchi et al.
Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 30(6), 687-690 (2014-06-13)
A fluorocarbon and hydrocarbon organic solvent mixture is known as a temperature-induced phase-separation solution. When a mixed solution of tetradecafluorohexane as a fluorocarbon organic solvent and hexane as a hydrocarbon organic solvent (e.g., 71:29 volume ratio) was delivered in a

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service