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333972

Sigma-Aldrich

Zirconium(IV) propoxide solution

70 wt. % in 1-propanol

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Synonym(s):
Tetrapropyl zirconate
Linear Formula:
Zr(OCH2CH2CH3)4
CAS Number:
Molecular Weight:
327.57
Beilstein/REAXYS Number:
3679533
MDL number:
PubChem Substance ID:
NACRES:
NA.23

form

solution

Quality Level

composition

Zr, 18.1-22.3% gravimetric

reaction suitability

core: zirconium
reagent type: catalyst

concentration

70 wt. % in 1-propanol

refractive index

n20/D 1.451

bp

208 °C/0.1 mmHg

density

1.044 g/mL at 25 °C

SMILES string

CCCO[Zr](OCCC)(OCCC)OCCC

InChI

1S/4C3H7O.Zr/c4*1-2-3-4;/h4*2-3H2,1H3;/q4*-1;+4

InChI key

XPGAWFIWCWKDDL-UHFFFAOYSA-N

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1 of 4

This Item
325252253081333948
vibrant-m

333972

Zirconium(IV) propoxide solution

vibrant-m

253081

Titanium(IV) propoxide

vibrant-m

333948

Zirconium(IV) butoxide solution

composition

Zr, 18.1-22.3% gravimetric

composition

Ti, 9-10.5% gravimetric

composition

-

composition

-

concentration

70 wt. % in 1-propanol

concentration

75 wt. % in isopropanol

concentration

-

concentration

80 wt. % in 1-butanol

density

1.044 g/mL at 25 °C

density

0.995 g/mL at 25 °C

density

1.033 g/mL at 25 °C (lit.)

density

1.049 g/mL at 25 °C

bp

208 °C/0.1 mmHg

bp

-

bp

170 °C/3 mmHg (lit.)

bp

-

refractive index

n20/D 1.451

refractive index

n20/D 1.4935

refractive index

n20/D 1.499 (lit.)

refractive index

n20/D 1.466

Application

Zirconium(IV) propoxide solution is a metal alkoxide solution that is highly reactive with water. It can be used as a precursor material for the synthesis of zirconium oxide thin films by atmospheric pressure electrospray. Zirconium(IV) propoxide can also be used in the preparation of stable sols for potential usage in optical, electronic and magnetic applications.

signalword

Danger

Hazard Classifications

Eye Dam. 1 - Flam. Liq. 3 - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

82.9 °F - closed cup

flash_point_c

28.3 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Synthesis of highly stabilized zirconia sols from zirconium n-propoxide-diglycol system
Zhao J, et al.
Journal of Non-Crystalline Solids, 261(1-3), 15-20 (2000)
Heine, M.C.; et al.
Combustion and Flame, 144 (4), 809-820 (2006)
Ruohong Sui et al.
Langmuir : the ACS journal of surfaces and colloids, 22(9), 4390-4396 (2006-04-19)
The objective of the present study was to synthesize porous ZrO2 aerogels with a nanostructure via a direct sol-gel route in the green solvent supercritical carbon dioxide (scCO2). The synthesis involved the coordination and polycondensation of a zirconium alkoxide using
Sol-gel templating of membranes to form thick, porous titania, titania/zirconia and titania/silica films
Schattka JH, et al.
Journal of Materials Chemistry, 16(15), 1414-1420 (2006)
In Situ Enrichment of Phosphopeptides on MALDI Plates Functionalized by Reactive Landing of Zirconium (IV)- n-Propoxide Ions
Blacken GR, et al.
Analytical Chemistry, 79(14), 5449-5456 (2007)

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