337773

Chlorodiisopropylphosphine

96%, liquid

• Synonym(s): Diisopropylphosphine chloride
• Linear Formula: [(CH₃)₂CH]₂PCl
• CAS Number: 40244-90-4
• Molecular Weight: 152.60
• MDL number: MFCD00015027
• UNSPSC Code: 12352001
• PubChem Substance ID: 24860498
• NACRES: NA.22

Properties

• Product Name: Chlorodiisopropylphosphine, 96%
• Quality Level: 100
• assay: 96%
• form: liquid
• reaction suitability: reagent type: ligand; reaction type: Arylations
• refractive index: n20/D 1.475 (lit.)
• bp: 69 °C/33 mmHg (lit.)
• density: 0.959 g/mL at 25 °C (lit.)
• functional group: phosphine
• SMILES string: CC(C)P(Cl)C(C)C
• InChI: 1S/C6H14ClP/c1-5(2)8(7)6(3)4/h5-6H,1-4H3
• InChI key: JZPDBTOWHLZQFC-UHFFFAOYSA-N

Description

Application

Chlorodiisopropylphosphine can be used:

• To synthesize p-styryldiisopropylphosphine by reacting with 4-chlorostyrene via Grignard reaction.
• As a phosphination reagent in combination with [Cp2Zr(1-butene)(DMAP)] (Cp=cyclopentadienyl; DMAP= 4-(dimethylamino)pyridine)) for the zirconophosphination of alkynes to form zirconoalkenylphosphines.
• A luminescent mixed-donor platinum POCN pincer complex via cyclometalation process.

Safety Information

• pictograms: GHS02,GHS05
• signalword: Danger
• hcodes: H225,H314
• pcodes: P210 - P233 - P240 - P280 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Flam. Liq. 2 - Skin Corr. 1B
• Storage Class: 3 - Flammable liquids
• wgk_germany: WGK 3
• flash_point_f: 39.2 °F - closed cup
• flash_point_c: 4 °C - closed cup
• ppe: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter