Skip to Content
MilliporeSigma
All Photos(2)

Documents

341622

Sigma-Aldrich

Bromopentacarbonylmanganese(I)

98%

Synonym(s):

Bromopentacarbonylmanganese(I), Manganese pentacarbonyl bromide

Sign Into View Organizational & Contract Pricing
All Photos(2)

About This Item

Linear Formula:
BrMn(CO)5
CAS Number:
14516-54-2
Molecular Weight:
274.89
EC Number:
238-522-8
MDL number:
MFCD00049806
UNSPSC Code:
12352103
PubChem Substance ID:
24860973
NACRES:
NA.23

assay

98%

form

powder or crystals

reaction suitability

core: manganese
reagent type: catalyst

storage temp.

2-8°C

SMILES string

[Mn]Br.[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

InChI

1S/5CO.BrH.Mn/c5*1-2;;/h;;;;;1H;/q;;;;;;+1/p-1

InChI key

OESORJHGSXJTKX-UHFFFAOYSA-M

Application

Bromopentacarbonylmanganese(I) can be used as:
  • A precursor to synthesize manganese complex, [Mn(CO)5H], which was then used as a catalyst in the reduction of levulinic acid (LA) to methyltetrahydrofuran (MTHF) and the reductive amination of LA to N-substituted pyrrolidines.
  • A precursor to prepare Mn(I) complexes bearing bifunctional ligands, which are used as catalysts for the transfer-hydrogenation of various ketones and imines using 2-propanol as the hydrogen donor.
  • A catalyst in the selective C2-H activation reactions.


pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Customers Also Viewed

Slide 1 of 2

1 of 2

Manganese(II) bromide 98%

Sigma-Aldrich

223646

Manganese(II) bromide

Cobalt carbonyl moistened with hexane (hexane 1-10%), ≥90% (Co)

Sigma-Aldrich

60811

Cobalt carbonyl

Miguel N Pinto et al.
Journal of controlled release : official journal of the Controlled Release Society, 264, 192-202 (2017-09-04)
The gaseous signaling molecule carbon monoxide (CO) has recently been recognized for its wide range of physiological activity as well as its antineoplastic properties. However, site-specific delivery of this noxious gas presents a major challenge in hospital settings. In this
Felipe López-Saucedo et al.
Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine, 156, 108983-108983 (2019-11-25)
We report on the synthesis of new manganese carbonyls-based materials prepared using gamma-rays radiation (at doses of 10 and 40 kGy) as energy source. Characterization was achieved using nuclear magnetic resonance, infrared spectroscopy, elemental analysis, single-crystal X-ray diffraction, differential scan calorimetry
Ken T Ngo et al.
Journal of the American Chemical Society, 139(7), 2604-2618 (2017-01-25)
Electrocatalytic reduction of CO

Articles

Progress in Spintronic Materials

Spintronics offer breakthroughs over conventional memory/logic devices with lower power, leakage, saturation, and complexity.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service