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Chlorobis(cyclooctene)iridium(I)dimer

97%

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Synonym(s):
[Ir(coe)2Cl]2, Di-μ-chlorotetrakis(cyclooctene)diiridium
Empirical Formula (Hill Notation):
C32H56Cl2Ir2
CAS Number:
Molecular Weight:
896.13
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

97%

form

powder

reaction suitability

core: iridium
reagent type: catalyst

mp

160-165 °C (dec.) (lit.)

SMILES string

Cl[Ir].Cl[Ir].[CH]1[CH]CCCCCC1.[CH]2[CH]CCCCCC2.[CH]3[CH]CCCCCC3.[CH]4[CH]CCCCCC4

InChI

1S/4C8H14.2ClH.2Ir/c4*1-2-4-6-8-7-5-3-1;;;;/h4*1-2H,3-8H2;2*1H;;/q;;;;;;2*+1/p-2/b4*2-1-;;;;

InChI key

WBRREXQCZAFSKS-XFCUKONHSA-L

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vibrant-m

683094

HS157

Quality Level

100

Quality Level

200

Quality Level

100

Quality Level

100

form

powder

form

powder

form

-

form

powder

reaction suitability

core: iridium, reagent type: catalyst

reaction suitability

core: iridium, reaction type: C-H Activation, reagent type: catalyst

reaction suitability

core: iridium, reagent type: catalyst

reaction suitability

core: rhodium, reagent type: catalyst

mp

160-165 °C (dec.) (lit.)

mp

205 °C (dec.) (lit.)

mp

224 °C (dec.) (lit.)

mp

190 °C (dec.) (lit.)

Application

Catalyst for:
  • Isomerization-hydroboration reactions with nido-carboranyldiphosphine as stabilizing ligand
  • Hydrogen peroxide oxidation of hydroxamic acids and their subsequent hetero Diels-Alder cycloaddition reactions
  • Immobilization of organic functional groups onto solid supports through vinylsilane coupling reactions
  • Alkylation reactions
  • Guerbet reaction
  • Allylic amination reactions in a DNA-diene-iridium(I) hybrid system
  • Asymmetric hydroamination reactions
Chlorobis(cyclooctene)iridium(I)dimer can be used as a catalyst for:
  • Isomerization-hydroboration reactions with nido-carboranyldiphosphine as stabilizing ligand.
  • Hydrogen peroxide oxidation of hydroxamic acids and their subsequent hetero Diels-Alder cycloaddition reactions.
  • Immobilization of organic functional groups onto solid supports through vinylsilane coupling reactions.
  • Alkylation reactions.
  • Guerbet reaction.
  • Allylic amination reactions using a DNA-diene-iridium(I) hybrid system.
  • Asymmetric hydroamination reactions.

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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