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391573

Sigma-Aldrich

1-Bromopyrene

96%

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Empirical Formula (Hill Notation):
C16H9Br
CAS Number:
Molecular Weight:
281.15
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

96%

form

powder

mp

102-105 °C (lit.)

SMILES string

Brc1ccc2ccc3cccc4ccc1c2c34

InChI

1S/C16H9Br/c17-14-9-7-12-5-4-10-2-1-3-11-6-8-13(14)16(12)15(10)11/h1-9H

InChI key

HYGLETVERPVXOS-UHFFFAOYSA-N

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1 of 4

This Item
124141213497157449
1-Bromopyrene 96%

391573

1-Bromopyrene

4-Bromostyrene contains 0.05% 3,5-di-tert-butylcatechol as inhibitor, 97%

124141

4-Bromostyrene

2-Hydroxycarbazole 97%

213497

2-Hydroxycarbazole

β-Bromostyrene 97%

157449

β-Bromostyrene

mp

102-105 °C (lit.)

mp

-

mp

270-273 °C (lit.)

mp

7 °C (lit.)

form

powder

form

liquid

form

solid

form

liquid

General description

1-Bromopyrene, a polycyclic aromatic hydrocarbon (PAH), is a mono bromo substituted pyrene derivative. Its synthesis has been reported. Its gas phase UV-absorption spectra in the UV wavelength range at elevated temperature has been studied. Electron affinitiy (EA) of 1-bromopyrene has been investigated using electron attachment desorption chemical ionization mass spectrometry (DCI-MS) and triple quadrupole tandem mass spectrometry. It participates in the synthesis of novel ruthenium (II) bipyridine or terpyridine complexes bearing pyrene moiety. The reaction of 1-bromopyrene cation radical with water in acetonitrile has been analyzed using the electron transfer stopped-flow (ETSF) method.

Application

1-Bromopyrene is suitable reagent used in the comparative study of effect of substituents of some pyrene derivatives in inducing phototoxicity, DNA damage and repair in human skin keratinocytes and light-induced lipid peroxidation in methanol. It is suitable reagent used in the study to investigate the UV photon-assisted thermal decomposition of PAHs at elevated temperature.
1-Bromopyrene may be used as a standard to compare its spectral properties with that of pyrene based fluorescence probe. It may be used to study the effects of the addition of halogen hetero-atoms on the vapor pressures and thermodynamics of polycyclic aromatic hydrocarbons.
It may be used in the synthesis of the following:
  • 2-methyl-4-pyren-1-yl-but-3-yn-2-ol
  • 1-ethynylpyrene
  • silsesquioxane (SSQ) based hybrid
  • ruthenium nanoparticles functionalized with pyrene moiety
  • mono- and di-pyrenyl perfluoroalkanes
  • oligo(1-bromopyrene)(OBrP) films
  • dinitropyrene-derived DNA adduct

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Organic-inorganic hybrids based on pyrene functionalized octavinylsilsesquioxane cores for application in OLEDs.
Mee Yoon Lo et al.
Journal of the American Chemical Society, 129(18), 5808-5809 (2007-04-13)
UV photon-assisted incineration of polycyclic aromatic hydrocarbons at elevated temperatures between 150 and 800?C.
Thony A and Rossi MJ.
Journal of Photochemistry and Photobiology A: Chemistry, 109(3), 267-280 (1997)
Gas-phase UV spectroscopy of anthracene, xanthone, pyrene, 1-bromopyrene and 1, 2, 4-trichlorobenzene at elevated temperatures.
Thony A and Rossi MJ.
Journal of Photochemistry and Photobiology A: Chemistry, 104(1), 25-33 (1997)
Jillian L Goldfarb et al.
The Journal of chemical thermodynamics, 40(3), 460-466 (2008-03-01)
Knowledge of vapor pressures of high molar mass organics is essential to predicting their behavior in combustion systems as well as their fate and transport within the environment. This study involved polycyclic aromatic compounds (PACs) containing halogen hetero-atoms, including bromine
Shu-Wen Yang et al.
The journal of physical chemistry. B, 109(35), 16628-16635 (2006-07-21)
An attempt to tune the electronic properties of pyrene (Py) by coupling it with a strong electron donor (-PhNMe2, DMA)/acceptor (anthronitrile, AN) through an ethynyl bridge has been undertaken. A moderate electron donor (iPrOPh-, IPP)/acceptor (2-quinolinyl, 2Q) has also been

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