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395099

Sigma-Aldrich

Tris(4-fluorophenyl)phosphine

greener alternative

98%

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Synonym(s):
Tri-(p-fluorophenyl)phosphine
Linear Formula:
(FC6H4)3P
CAS Number:
Molecular Weight:
316.26
Beilstein/REAXYS Number:
919838
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

98%

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

mp

79-83 °C (lit.)

functional group

phosphine

greener alternative category

SMILES string

Fc1ccc(cc1)P(c2ccc(F)cc2)c3ccc(F)cc3

InChI

1S/C18H12F3P/c19-13-1-7-16(8-2-13)22(17-9-3-14(20)4-10-17)18-11-5-15(21)6-12-18/h1-12H

InChI key

GEPJPYNDFSOARB-UHFFFAOYSA-N

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This Item
327697510017902292
Tris(4-fluorophenyl)phosphine 98%

395099

Tris(4-fluorophenyl)phosphine

EvanPhos ≥95%

902292

EvanPhos

assay

98%

assay

97%

assay

98%

assay

≥95%

functional group

phosphine

functional group

phosphine

functional group

phosphine

functional group

phosphine

mp

79-83 °C (lit.)

mp

134-135 °C (lit.)

mp

184-187 °C (lit.)

mp

131-133 °C

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

greener alternative category

Aligned,

greener alternative category

, Aligned

greener alternative category

, Aligned

greener alternative category

Aligned,

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Ligand for rhodium-catalyzed oxygenative addition to terminal alkynes for a greener synthesis esters, amides, and carboxylic acids.

Rhodium-Catalyzed Oxygenative Addition to Terminal Alkynes for the Synthesis of Esters, Amides, and Carboxylic Acids

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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