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416126

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Trimethylolpropane diallyl ether

90%

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Synonym(s):
2,2-Bis(allyloxymethyl)-1-butanol
Linear Formula:
C2H5C(CH2OCH2CH=CH2)2CH2OH
CAS Number:
Molecular Weight:
214.30
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.23

Quality Level

assay

90%

form

liquid

refractive index

n20/D 1.458 (lit.)

bp

135 °C/13 mmHg (lit.)

density

0.955 g/mL at 25 °C (lit.)

SMILES string

CCC(CO)(COCC=C)COCC=C

InChI

1S/C12H22O3/c1-4-7-14-10-12(6-3,9-13)11-15-8-5-2/h4-5,13H,1-2,6-11H2,3H3

InChI key

BDKDHWOPFRTWPP-UHFFFAOYSA-N

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This Item
416118416134246840
vibrant-m

416126

Trimethylolpropane diallyl ether

vibrant-m

416118

Trimethylolpropane allyl ether

vibrant-m

416134

Di(trimethylolpropane)

vibrant-m

246840

Trimethylolpropane trimethacrylate

density

0.955 g/mL at 25 °C (lit.)

density

1.01 g/mL at 25 °C (lit.)

density

-

density

1.06 g/mL at 25 °C (lit.)

refractive index

n20/D 1.458 (lit.)

refractive index

n20/D 1.467 (lit.)

refractive index

-

refractive index

n20/D 1.472 (lit.)

bp

135 °C/13 mmHg (lit.)

bp

160 °C/33 mmHg (lit.)

bp

215 °C/4 mmHg (lit.)

bp

-

form

liquid

form

viscous liquid

form

-

form

-

Quality Level

200

Quality Level

200

Quality Level

200

Quality Level

200

General description

Trimethylolpropane diallyl ether (TMPAE) is an unsaturated allyl ether that can be synthesized by Williamson esterification reaction in the presence of trimethylolpropane, sodium hydroxide, and allyl chloride as starting materials.

Application

TMPAE can be used in the synthesis of isophorone diisocyanate (IPDI) based tetracene monomers which can further be used in the formation of polymer dispersed liquid crystals. It can also be used in the synthesis of allyl ether based dendrimers that find potential usage in coatings.

Other Notes

remainder monoethers and triethers

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

244.4 °F - closed cup

flash_point_c

118 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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Thermal and Mechanical Properties of Cross-Linked Photopolymers Based on Multifunctional Thiol- Urethane Ene Monomers
Senyurt AF, et al.
Macromolecules, 40(9), 3174-3182 (2007)
Optimization of Synthetical Technology for Trimethylolpropane Diallyl Ether by Response Surface Method
ZHANG JT, et al.
Shanghai Kou Qiang yi Xue = Shanghai Journal of Stomatology, 2(25), 7671-7678 (2010)
Synthesis and thiol-ene photopolymerization of allyl-ether functionalized dendrimers
Nilsson C, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 46(4), 1339-1348 (2008)
Visible light induced polymerization of maleimide-vinyl and maleimide-allyl ether based systems
Burget D, et al.
Polymer, 44(25), 7671-7678 (2003)

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