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429120

Sigma-Aldrich

3-Methoxybenzyl bromide

98%

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Synonym(s):
1-Bromomethyl-3-methoxybenzene
Linear Formula:
CH3OC6H4CH2Br
CAS Number:
Molecular Weight:
201.06
MDL number:
PubChem Substance ID:
NACRES:
NA.22

assay

98%

form

liquid

refractive index

n20/D 1.575 (lit.)

bp

152 °C (lit.)

density

1.436 g/mL at 25 °C (lit.)

SMILES string

COc1cccc(CBr)c1

InChI

1S/C8H9BrO/c1-10-8-4-2-3-7(5-8)6-9/h2-5H,6H2,1H3

InChI key

ZKSOJQDNSNJIQW-UHFFFAOYSA-N

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1 of 4

This Item
B17905760048529990
vibrant-m

429120

3-Methoxybenzyl bromide

vibrant-m

B17905

Benzyl bromide

vibrant-m

760048

2-Chloro-4-methoxybenzyl bromide

vibrant-m

529990

4-Bromomethyl benzoyl bromide

assay

98%

assay

98%

assay

97%

assay

96%

form

liquid

form

liquid

form

solid

form

-

bp

152 °C (lit.)

bp

198-199 °C (lit.)

bp

-

bp

100-112 °C/0.5 mmHg (lit.)

density

1.436 g/mL at 25 °C (lit.)

density

1.438 g/mL at 25 °C (lit.)

density

-

density

-

refractive index

n20/D 1.575 (lit.)

refractive index

n20/D 1.575 (lit.)

refractive index

-

refractive index

-

General description

3-Methoxybenzyl bromide is a benzyl bromide derivative.

Application

3-Methoxybenzyl bromide (1-bromomethyl-3-methoxybenzene) may be used in the diastereoselective alkylation of vicinal dianions of chiral succinic acid derivatives.
It may be used in the synthesis of the following:
  • 6-(3-methoxyphenyl)-hexane-2,4-dione
  • N-(3-methoxybenzyl)-N-(1-methyl-1-phenylethyl)-amine
  • 2-(3-methoxybenzyl)-3-[(1R)-7,7-dimethyl-2-oxobicyclo[2.2.1]hept-1-yl]-(3S)-2-thionia-bicyclo [2.2.1]- heptane tetrafluoroborate
  • 1-(3-methoxybenzyl)-5-(1-methyl-1H-imidazol-5-yl)-1H-1,2,3-triazole

Pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class

8A - Combustible, corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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