526304
Cyanoborohydride, polymer supported
macroporous, 20-50 mesh, extent of labeling: ~2.0-3.5 mmol/g loading
Synonym(s):
Cyanoborohydride on Amberlite™ IRA-400
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About This Item
Recommended Products
form
macroporous
Quality Level
reaction suitability
reaction type: solution phase peptide synthesis
reactivity: imine reactive
extent of labeling
~2.0-3.5 mmol/g loading
particle size
20-50 mesh
mp
>300 °C (lit.)
storage temp.
2-8°C
General description
Cyanoborohydride, polymer supported: is a polymer-supported reducing agent used in reductive amination reactions at room temperature.
Application
Polymer supported cyanoborohydride (PSCBH) has been used in the reductive alkylation aminocyclitols for the preparation of corresponding secondary amines.
It can also be used:
It can also be used:
- In combination with manganese dioxide (MnO2) for one-pot conversion of alcohols to secondary or tertiary amines.
- In the synthesis of natural products, (±)-oxomaritidine and (±)-epimaritidine.
Legal Information
Amberlite is a trademark of DuPont de Nemours, Inc.
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Certificates of Analysis (COA)
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Find documentation for the products that you have recently purchased in the Document Library.
J. Chem. Soc., Perkin Trans., 2239-2239 (1998)
Small-Scale One-Pot Reductive Alkylation of Unprotected Aminocyclitols with Supported Reagents
Synthesis, 2008(19), 3167-3170 (2008)
In situ oxidation- imine formation- reduction routes from alcohols to amines
Organic Letters, 3(11), 1637-1639 (2001)
Journal of the Chemical Society. Chemical Communications, 1088-1088 (1978)
J. Chem. Soc., Perkin Trans., 3127-3127 (1998)
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