538647

1-Fluorododecane

98%

• Synonym(s): n-Dodecyl fluoride
• Linear Formula: F(CH₂)₁₁CH₃
• CAS Number: 334-68-9
• Molecular Weight: 188.33
• EC Number: 206-381-1
• MDL number: MFCD00013580
• UNSPSC Code: 12352100
• PubChem Substance ID: 24878349
• NACRES: NA.22

Properties

• Quality Level: 100
• assay: 98%
• refractive index: n20/D 1.42 (lit.)
• density: 0.807 g/mL at 25 °C (lit.)
• functional group: alkyl halide; fluoro
• SMILES string: CCCCCCCCCCCCF
• InChI: 1S/C12H25F/c1-2-3-4-5-6-7-8-9-10-11-12-13/h2-12H2,1H3
• InChI key: YHYBNVZCQIDLSQ-UHFFFAOYSA-N

Description

General description

1-Fluorododecane is a long chain 1-fluoroalkane. It can be synthesized from the reaction between 1-dodecanol, N,N-diethyl-α,α-difluoro-[3,5-bis(1H,1H,2H,2H-perfluorodecyl)benzyl]amine and heptane. 1-Fluorododecane undergoes reaction with dibromomethane and titanocene dichloride in the presence of triethyl aluminium (Et₃Al) to afford a mixture of 1-chlorododecane and 1-bromododecane. 1-Fluorododecane can also be prepared from 1-hydroxydodecane.

Safety Information

• pictograms: GHS06
• signalword: Danger
• hcodes: H300,H413
• pcodes: P273 - P301 + P310 + P330
• Hazard Classifications: Acute Tox. 2 Oral - Aquatic Chronic 4
• Storage Class: 6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• wgk_germany: WGK 3
• flash_point_f: 223.0 °F - closed cup
• flash_point_c: 106.1 °C - closed cup
• ppe: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter