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659223

Sigma-Aldrich

Poly(2,5-bis(3-sulfonatopropoxy)-1,4-phenylene, disodium salt-alt-1,4-phenylene)

light emitting, fluorescence λem 424 nm in H2O

Synonym(s):
(−)PPP
Linear Formula:
(C18H18Na2O8S2)n
MDL number:
NACRES:
NA.23

Quality Level

form

solid

solubility

H2O: soluble

λmax

208 nm (in deoxygenated water)(lit.)

fluorescence

λex 322 nm; λem 424 nm in H2O
λex 363 nm; λem 410 nm in H2O(lit.)
λem 424 nm in H2O

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This Item
678066659738182354
solubility

H2O: soluble

solubility

-

solubility

THF: insoluble, but swells, chloroform: soluble, hexane: insoluble, but swells

solubility

-

λmax

208 nm (in deoxygenated water)(lit.)

λmax

340 nm

λmax

-

λmax

-

fluorescence

λex 322 nm; λem 424 nm in H2O

fluorescence

λem 401 nm in chloroform

fluorescence

-

fluorescence

-

General description

Poly(2,5-bis(3-sulfonatopropoxy)-1,4-phenylene, disodium salt-alt-1,4-phenylene) (PPP-OPSO3) is a water soluble conjugating polymer that can be used as a donor molecule. It has a poly(p-phenylene) skeleton with each repeating unit having two phenylene groups. It can be used for a variety of optoelectronic applications.

Application

PPP-OPSO3 is a π-conjugating polymer that can be used in organic light emitting diodes (OLEDs), thin film transistors (TFTs), and flexible organic solar cells.
A water-soluble polyanionic blue-light emitting polymer.

Features and Benefits

Ready to use, water-soluble light, emitting material, more soluble than MPS-PPV.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Controlled energy transfer between isolated donor-acceptor molecules intercalated in thermally self-ensemble two-dimensional hydrogen bonding cages
Al Attar HA and Monkman AP
Physical Review. B, Condensed Matter and Materials Physics, 86(23), 235420-235420 (2012)
Room-Temperature Phosphorescence From Films of Isolated Water-Soluble Conjugated Polymers in Hydrogen-Bonded Matrices
Al-Attar HA and Monkman AP
Advances in Functional Materials, 22(18), 3824-3832 (2012)
Conjugated Polymer Nanoparticles Having Modified Band Gaps Assembled into Nano-and Micropatterned Organic Light-Emitting Diodes
Herrera M, et al.
ACS Applied Nano Materials, 2(1), 577-585 (2018)
Reynolds, J.R., et al.
Macromolecules, 31, 964-964 (1998)

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