923451

(PhMPhos)PdCl₂

complex with CH₂Cl₂

• Synonym(s): 1-Diadamantylphosphino-1′-diphenylphosphinoferrocene palladium dichloride
• Empirical Formula (Hill Notation): C₄₂H₄₈Cl₂FeP₂Pd
• CAS Number: 2768152-18-5
• Molecular Weight: 847.95
• UNSPSC Code: 12352101
• NACRES: NA.21

Properties

• Quality Level: 100
• form: powder
• reaction suitability: reagent type: catalyst; reaction type: Cross Couplings

Description

Application

(PhMPhos)PdCl₂ is an unsymmetrical ferrocene-based Pd-catalyst. The MPhos series of ligands are unsymmetrical diphosphino-ferrocenes bearing a bulky adamantyl group. (PhMPhos)PdCl₂ can be used for a variety of cross-coupling transformations, including Suzuki coupling, C-P coupling, and Csp²-Csp³ coupling. Demonstrated Csp²-Csp³ couplings include Murahashi-Feringa Coupling (Alkyl-Li), Kumada-Corriu coupling (Alkyl-MgX), Negishi coupling (Alkyl-ZnX) and Suzuki–Miyaura coupling (Alkyl-B(OR₂)).

Learn more about MPhos ligands and catalysts

Other Notes

Tunable Unsymmetrical Ferrocene Ligands Bearing a Bulky Di-1-adamantylphosphino Motif for Many Kinds of Csp²–Csp³ Couplings

Safety Information

• pictograms: GHS08,GHS07
• signalword: Warning
• hcodes: H315,H319,H351
• pcodes: P202 - P264 - P280 - P302 + P352 - P305 + P351 + P338 - P308 + P313
• Hazard Classifications: Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable