B22984
O-Benzylhydroxylamine hydrochloride
99%
Synonym(s):
Benzyloxyamine hydrochloride
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About This Item
Linear Formula:
C6H5CH2ONH2 · HCl
CAS Number:
Molecular Weight:
159.61
Beilstein/REAXYS Number:
3687991
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
assay
99%
form
crystals
mp
238 °C (subl.) (lit.)
SMILES string
Cl.NOCc1ccccc1
InChI
1S/C7H9NO.ClH/c8-9-6-7-4-2-1-3-5-7;/h1-5H,6,8H2;1H
InChI key
HYDZPXNVHXJHBG-UHFFFAOYSA-N
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Related Categories
Application
Effective reagent used to prepare α-hydroxybenzylamines from α-hydroxyketones.
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Irrit. 2 - Skin Sens. 1
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
ppe
Eyeshields, Gloves, type N95 (US)
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G Stampf et al.
Die Pharmazie, 35(1), 43-44 (1980-01-01)
The study of the blood levels and tissue concentrations in mice to which 14C-benzyloxyamine hydrochloride was applied in the form of a spray and of a suspensoid aerosol evidenced the good abosrption of this pharmacon. Maximum blood levels were observed
[Thermographic analysis of precipitates formed by the interaction of active ingredients and additives].
G Stampf et al.
Acta pharmaceutica Hungarica, 53(6), 268-272 (1983-11-01)
Samia Far et al.
Journal of peptide science : an official publication of the European Peptide Society, 11(7), 424-430 (2005-01-11)
The synthesis of glyoxylyl peptides by coupling the masked glyoxylic acid derivative (FmocNH)(2)CHCO(2)H, 1, to a peptidyl resin assembled using Fmoc/tert-butyl chemistry has been described recently. Deprotection and cleavage of the peptide from the solid support using TFA was followed
Han Fu et al.
Journal of combinatorial chemistry, 9(5), 804-810 (2007-08-11)
A highly regioselective and traceless solid-phase route to 1,7,8-trisubstituted purines has been developed. This methodology could be extended to the preparation of 8-azapurines and [i]-condensed purines. A representative set of 17 purines, azapurines, and [i]-condensed purines was synthesized. This paper
G Cardillo et al.
Organic letters, 3(8), 1165-1167 (2001-05-12)
[reaction: see text]. The 1,4-addition of O-benzylhydroxylamine to alpha,beta-unsaturated imide 1 in the presence of BF3.Et2O proceeds with the preferential attack of the nucleophile on the Cbeta-re face. To explain this unexpected reactivity 1H, 13C, and 11B NMR investigations have
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