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MilliporeSigma

71840

Sigma-Aldrich

Sodium perborate tetrahydrate

purum p.a., 96% (RT)

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About This Item

Linear Formula:
NaBO3 · 4H2O
CAS Number:
Molecular Weight:
153.86
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.21
Assay:
96% (RT)
Form:
powder or crystals
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grade

purum p.a.

Quality Level

assay

96% (RT)

form

powder or crystals

concentration

≥10% (active oxygen)

pH

10-10.4 (25 °C, 10 g/L)

mp

60 °C (dec.) (lit.)

anion traces

chloride (Cl-): ≤500 mg/kg
sulfate (SO42-): ≤6000 mg/kg

cation traces

Ca: ≤200 mg/kg
Cd: ≤50 mg/kg
Co: ≤50 mg/kg
Cu: ≤50 mg/kg
Fe: ≤50 mg/kg
K: ≤100 mg/kg
Ni: ≤50 mg/kg
Pb: ≤50 mg/kg
Zn: ≤50 mg/kg

SMILES string

O.O.O.O.[Na+].[O-]B1OO1

InChI

1S/BO3.Na.4H2O/c2-1-3-4-1;;;;;/h;;4*1H2/q-1;+1;;;;

InChI key

IBDSNZLUHYKHQP-UHFFFAOYSA-N

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General description

Sodium perborate tetrahydrate is a hydrated sodium salt. It participates in various oxidation reactions of anilines and sulfides.

Application

Sodium perborate tetrahydrate may be employed for the following studies:
  • Transformation of iodoarenes to (diacetoxyiodo)arenes.
  • Oxidation of Π-deficient azines to afford N-oxides.
  • Oxidation of sulfur containing heterocyclic compounds to afford S,S-dioxides.
  • Microwave-assisted oxidative hydration of various aromatic and aliphatic nitriles.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Repr. 1B - STOT SE 3

target_organs

Respiratory system

Storage Class

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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Further functional group oxidations using sodium perborate.
McKillop A and Kemp D.
Tetrahedron, 45(11), 3299-3306 (1989)
Microwave-promoted transformation of nitriles to amides with aqueous sodium perborate.
Sharifi A, et al.
Synthetic Communications, 31(3), 431-434 (2001)
In vitro evaluation of the efficacy of 4 denture cleanser tabs against oral bacteria.
D L Alves et al.
Bulletin du Groupement international pour la recherche scientifique en stomatologie & odontologie, 50(1), 31-35 (2011-01-01)
D M P Spolidorio et al.
International journal of dental hygiene, 9(4), 279-283 (2011-03-02)
The aim of this study was to investigate the effectiveness of two alternatives methods for the disinfection of oral cleaning devices. One type of toothbrush and two types of tongue scrapers (steel and plastic) were tested in this study. Sixteen
Joseph Robin Mathai et al.
The New York state dental journal, 77(4), 48-53 (2011-09-08)
Acrylic resin bases of removable dentures attract stains and odor-producing organic and inorganic deposits. The use of chemical denture cleanser soaks is the most popular method of denture cleansing. This study was undertaken to compare the efficacy of two different

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