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72252

Sigma-Aldrich

Nickel(II) nitrate hexahydrate

puriss. p.a., ≥98.5% (KT)

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Linear Formula:
Ni(NO3)2 · 6H2O
CAS Number:
Molecular Weight:
290.79
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.21

grade

puriss. p.a.

Quality Level

assay

≥98.5% (KT)

form

crystals or chunks

mp

56 °C (lit.)

density

2.05 g/mL at 25 °C (lit.)

anion traces

chloride (Cl-): ≤10 mg/kg
sulfate (SO42-): ≤50 mg/kg

cation traces

Ca: ≤10 mg/kg
Cd: ≤10 mg/kg
Co: ≤100 mg/kg
Cu: ≤20 mg/kg
Fe: ≤10 mg/kg
K: ≤50 mg/kg
Na: ≤50 mg/kg
Pb: ≤10 mg/kg
Zn: ≤10 mg/kg

SMILES string

O.O.O.O.O.O.[Ni++].[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/2NO3.Ni.6H2O/c2*2-1(3)4;;;;;;;/h;;;6*1H2/q2*-1;+2;;;;;;

InChI key

AOPCKOPZYFFEDA-UHFFFAOYSA-N

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General description

Nickel(II) nitrate hexahydrate (Ni(NO3)2.6H2O) is a hydrated nickel(II) salt. Its thermal degradation has been investigated by thermogravimetric methods under quasi-isothermal conditions.

Application

Nickel(II) nitrate hexahydrate may be used as precursor for the synthesis of [Ni1/3Co1/3Mn1/3]O2 powders and Ni(II) oxide aerogels.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A - Eye Dam. 1 - Muta. 2 - Ox. Sol. 2 - Repr. 1B - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 1 Inhalation

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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Monolithic nickel (II)-based aerogels using an organic epoxide: the importance of the counterion.
Gash AE, et al.
Journal of Non-Crystalline Solids, 350, 145-151 (2004)
Marisa Freitas et al.
Biometals : an international journal on the role of metal ions in biology, biochemistry, and medicine, 26(1), 13-21 (2012-10-26)
Nickel is an ubiquitous transition metal that is industrially applied in many forms, which inevitably leads to a high degree of occupational and environmental exposure. Over-exposure to nickel can produce a variety of adverse effects on human health, including allergy
H Tanojo et al.
Acta dermato-venereologica. Supplementum, (212)(212), 19-23 (2002-01-23)
Allergic contact dermatitis due to nickel salts is common. It is therefore important to measure the permeation of these salts through the stratum corneum (SC), the primary rate-limiting domain in skin. An advanced diffusion system and analytical techniques now enable
Thermal decomposition of nickel nitrate hexahydrate, Ni(NO3)2?6H2O, in comparison to Co(NO3)2?6H2O and Ca(NO3)2?4H2O.
Brockner W, et al.
Thermochimica Acta, 456(1), 64-68 (2007)
Jun Li et al.
Journal of colloid and interface science, 332(1), 231-236 (2009-01-16)
In this paper, we report the successful synthesis of Ni(12)P(5) hollow spheres via a facile hydrothermal route, employing white phosphorus (WP) and nickel nitrate as the reactants in the presence of hexamethylenetetramine (HMT) and polyethylene glycol 10000 (PEG-10000). The phase

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