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G4878

Sigma-Aldrich

D-Glucosamine 6-phosphate sodium salt

≥98% (TLC)

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Empirical Formula (Hill Notation):
C6H14NO8P
CAS Number:
Molecular Weight:
259.15
MDL number:
PubChem Substance ID:
NACRES:
NA.25

Quality Level

assay

≥98% (TLC)

form

powder

technique(s)

thin layer chromatography (TLC): suitable

impurities

<12% water (Karl Fischer)

color

white to off-white

solubility

water: 50 mg/mL, clear, colorless to light yellow

cation traces

Na: <8.5%

storage temp.

−20°C

SMILES string

[Na].NC(C=O)C(O)C(O)C(O)COP(O)(O)=O

InChI

1S/C6H14NO8P.Na.H/c7-3(1-8)5(10)6(11)4(9)2-15-16(12,13)14;;/h1,3-6,9-11H,2,7H2,(H2,12,13,14);;

InChI key

QSNQAUAPIDIXHB-UHFFFAOYSA-N

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This Item
A4394G5509A9545
D-Glucosamine 6-phosphate &#8805;98% (TLC)

G5509

D-Glucosamine 6-phosphate

technique(s)

thin layer chromatography (TLC): suitable

technique(s)

thin layer chromatography (TLC): suitable

technique(s)

thin layer chromatography (TLC): suitable

technique(s)

thin layer chromatography (TLC): suitable

solubility

water: 50 mg/mL, clear, colorless to light yellow

solubility

water: 50 mg/mL, clear, colorless

solubility

water: 50 mg/mL, clear to hazy, colorless to almost colorless

solubility

water: 49.00-51.00 mg/mL, clear, colorless to yellow

form

powder

form

powder

form

powder

form

powder

storage temp.

−20°C

storage temp.

−20°C

storage temp.

−20°C

storage temp.

−20°C

color

white to off-white

color

white to light yellow

color

white

color

white to yellow cast

Application

Glucosamine 6-phosphate has been used to accelerate enzyme-cleavage of DNA plasmids.

Biochem/physiol Actions

D-Glucosamine 6-phosphate, the natural form of glucosamine, is a monosaccharide produced during hexosamine biosynthesis pathway

Other Notes

To gain a comprehensive understanding of our extensive range of Monosaccharides for your research, we encourage you to visit our Carbohydrates Category page.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


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Christina E Lünse et al.
ACS chemical biology, 6(7), 675-678 (2011-04-14)
The glmS-riboswitch is unique among riboswitch families as it represents a metabolite-dependent ribozyme that undergoes self-cleavage upon recognition of glucosamin-6-phosphate. The glmS-riboswitch is located in the 5'-untranslated region of bacterial genes involved in cell wall biosynthesis. Therefore, this riboswitch represents
Marie Valerio-Lepiniec et al.
Archives of biochemistry and biophysics, 498(2), 95-104 (2010-04-27)
Glucosamine-6-phosphate synthase (GlmS) is responsible for the first and rate-limiting step in the hexosamine biosynthetic pathway. It catalyzes the conversion of D-fructose-6P (F6P) into D-glucosamine-6P (GlcN6P) using L-glutamine (Gln) as nitrogen donor (synthase activity) according to an ordered bi-bi process
Kevin Klawuhn et al.
Chembiochem : a European journal of chemical biology, 11(18), 2567-2571 (2010-11-26)
The bacterial glmS ribozyme is mechanistically unique among both riboswitches and RNA catalysts. Its self-cleavage activity is the basis of riboswitch regulation of glucosamine-6-phosphate (GlcN6P) production, and catalysis requires GlcN6P as a coenzyme. Previous work has shown that the coenzyme
Phillip J McCown et al.
RNA (New York, N.Y.), 17(4), 728-736 (2011-03-04)
Self-cleaving glmS ribozymes selectively bind glucosamine-6-phosphate (GlcN6P) and use this metabolite as a cofactor to promote self-cleavage by internal phosphoester transfer. Representatives of the glmS ribozyme class are found in Gram-positive bacteria where they reside in the 5' untranslated regions
Magdalena Popowska et al.
Archives of microbiology, 194(4), 255-268 (2011-09-29)
The main aim of our study was to determine the physiological function of NagA enzyme in the Listeria monocytogenes cell. The primary structure of the murein of L. monocytogenes is very similar to that of Escherichia coli, the main differences

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