MilliporeSigma
Search Within
Applications
Content Type

Metathesis

Applied Filters:
facet applications:Metathesis
facet content type:Technical Article
N-Heterocyclic Carbene-Copper Complexes
N-Heterocyclic Carbene-Copper Complexes
N-Heterocyclic Carbene (NHC) Compounds
Rovis has demonstrated that triazolium salt in the presence of a base can act as an N-heterocyclic carbene organocatalyst1 in highly enantioselective intramolecular Stetter reactions.
Metathesis
Olefin metathesis is now a well-entrenched synthetic technique, and is a powerful method for the clean construction of innumerable classes of chemical architectures.
Rieke® Highly Reactive Metals
Metal-enhanced organic synthesis via organometallic intermediates is a widely used preparative route for thousands of organic compounds.
N-Heterocyclic Carbene (NHC) Ligands
Metal complex-catalyzed cross-coupling reactions of unactivated substrates introduce diverse phosphine ligands in chemical marketplace.
CBILS©
The use of CBILS© – Carbonate Based Ionic Liquid Synthesis – developed by the Austrian company proionic, offers one of the simplest, yet most elegant synthetic methods for the production of ionic liquids
Hydrosilylation Catalyst
This robust protocol for hydrosilylation of terminal acetylenes to give α-vinylsilanes using [Cp*Ru(MeCN)3]PF6, as well as a number of other catalysts for hydrosilylation, comes from the Trost group at Stanford University.
Ring-Closing Alkyne Metathesis (RCAM)
Alkyne metathesis has been a useful tool for C–C bond formation since the discovery of structurally well-defined metal alkylidynes by Schrock and coworkers.
N-Heterocyclic Carbene (NHC) Ligands
Emerging class of privileged ligands
Rh2(esp)2 Catalyst
New! Rh2(esp)2, and exceptionally efficient and selective catalyst for C-H amination.
TPGS-750-M: Second-Generation Amphiphile for Organometallic Chemistry in Water at Room Temperature
Lipshutz and co-workers have recently developed a second generation technology to their original PTS-enabling surfactant based on the polyoxyethanyl-α-tocopheryl succinate derivative, TPGS-750-M.
N-Heterocyclic Carbenes
NHC (N-heterocyclic carbenes) are ligands for rapid synthesis of novel organometallic complexes. NHC ligands have practical use when bound to metals.