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  • Dynamic multimodal holograms of conjugated organogels via dithering mask lithography.

Dynamic multimodal holograms of conjugated organogels via dithering mask lithography.

Nature materials (2021-01-06)
Jongwon Oh, Dahye Baek, Tae Kyung Lee, Dongwon Kang, Hyeri Hwang, Eun Min Go, Inkyu Jeon, Younghoon You, Changil Son, Dowon Kim, Minji Whang, Kibum Nam, Moonjeong Jang, Jung-Hoon Park, Sang Kyu Kwak, Jungwook Kim, Jiseok Lee
ABSTRACT

Polymeric materials have been used to realize optical systems that, through periodic variations of their structural or optical properties, interact with light-generating holographic signals. Complex holographic systems can also be dynamically controlled through exposure to external stimuli, yet they usually contain only a single type of holographic mode. Here, we report a conjugated organogel that reversibly displays three modes of holograms in a single architecture. Using dithering mask lithography, we realized two-dimensional patterns with varying cross-linking densities on a conjugated polydiacetylene. In protic solvents, the organogel contracts anisotropically to develop optical and structural heterogeneities along the third dimension, displaying holograms in the form of three-dimensional full parallax signals, both in fluorescence and bright-field microscopy imaging. In aprotic solvents, these heterogeneities diminish as organogels expand, recovering the two-dimensional periodicity to display a third hologram mode based on iridescent structural colours. Our study presents a next-generation hologram manufacturing method for multilevel encryption technologies.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
2-Hydroxy-2-methylpropiophenone, 97%
Sigma-Aldrich
1,6-Hexanediol diacrylate, technical grade, 80%