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  • Green chemiluminescence from a bis-cyclometalated iridium(III) complex with an ancillary bathophenanthroline disulfonate ligand.

Green chemiluminescence from a bis-cyclometalated iridium(III) complex with an ancillary bathophenanthroline disulfonate ligand.

The Analyst (2011-06-29)
Elizabeth M Zammit, Neil W Barnett, Luke C Henderson, Gail A Dyson, Ming Zhou, Paul S Francis
ABSTRACT

The reaction of a fluorinated iridium complex with cerium(IV) and organic reducing agents generates an intense emission with a significant hypsochromic shift compared to contemporary chemically-initiated luminescence from metal complexes.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Bathophenanthrolinedisulfonic acid disodium salt hydrate, ≥95%
Sigma-Aldrich
Bathophenanthrolinedisulfonic acid disodium salt hydrate, 98%
Supelco
Bathophenanthrolinedisulfonic acid disodium salt trihydrate, for the spectrophotometric det. of Fe, ≥98.0% (HPLC)