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746479

Sigma-Aldrich

Lithium bromide

anhydrous, free-flowing, Redi-Dri™, ReagentPlus®, ≥99%

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About This Item

Linear Formula:
LiBr
CAS Number:
7550-35-8
Molecular Weight:
86.85
EC Number:
231-439-8
MDL number:
MFCD00011077
UNSPSC Code:
12352302
PubChem Substance ID:
329765771
NACRES:
NA.21
assay:
≥99%
grade:
anhydrous
form:
powder

grade

anhydrous

Quality Level

100

vapor pressure

1 hPa ( 748 °C)

product line

ReagentPlus®
Redi-Dri™

assay

≥99%

form

powder

quality

free-flowing

pH

7 (20 °C, 10 g/L)

mp

550 °C (lit.)

SMILES string

[Li+].[Br-]

InChI

1S/BrH.Li/h1H;/q;+1/p-1

InChI key

AMXOYNBUYSYVKV-UHFFFAOYSA-M

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General description

Lithium bromide is a versatile reagent that is commonly used as a nucleophilic brominating reagent. It is also employed as a Lewis acid catalyst and a mediator in various reactions.

Application

Lithium bromide can be used as a catalyst in the:
  • Solvent-free condensation of arylene diamines and esters to synthesize 2-substituted benzimidazoles and imidazopyridines.
  • Three-component condensation of aldehydes, β-ketoesters, and urea to synthesize dihydropyrimidinones via Biginelli reaction.
  • Solvent-free Ehrlich-Sachs reaction.

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
Redi-Dri is a trademark of Sigma-Aldrich Co. LLC

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pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1

Storage Class

13 - Non Combustible Solids

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
0000414178
0000414177
0000414177
0000414178
MKCV1733

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