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578703

Sigma-Aldrich

Dichloro(3-methyl-2-butenylidene)bis(tricyclopentylphosphine)ruthenium(II)

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About This Item

Empirical Formula (Hill Notation):
C35H62Cl2P2Ru
CAS Number:
220883-08-9
Molecular Weight:
716.79
MDL number:
MFCD04039971
UNSPSC Code:
12352300
PubChem Substance ID:
24880945

form

solid

mp

94-96 °C (lit.)

storage temp.

2-8°C

SMILES string

Cl[Ru]Cl.[CH][CH][C](C)C.C1CCC(C1)P(C2CCCC2)C3CCCC3.C4CCC(C4)P(C5CCCC5)C6CCCC6

InChI

1S/2C15H27P.C5H8.2ClH.Ru/c2*1-2-8-13(7-1)16(14-9-3-4-10-14)15-11-5-6-12-15;1-4-5(2)3;;;/h2*13-15H,1-12H2;1,4H,2-3H3;2*1H;/q;;;;;+2/p-2

InChI key

UCDVULRIJNJVEV-UHFFFAOYSA-L

Application

Metathesis: Ruthenium-Based Metathesis Catalysts

  • Reactant for synthesis of ruthenium olefin metathesis catalysts

  • Catalyst for ring-opening metathesis polymerization
Kinetic application profile similar to that of Grubbs 1st Generation Catalyst.

Other Notes

NO BULK ORDERS

Legal Information

US Patent No. 5,969,170 and foreign equivalents apply. Sale of this product conveys to the buyer a limited-use research license. For questions, please contact us at aldrich@sial.com

Pictograms

Flame
GHS02

Signal Word

Warning

Hazard Statements

H228

Precautionary Statements

P210

Hazard Classifications

Flam. Sol. 2

Storage Class Code

4.1B - Flammable solid hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
01729KH
15315JA

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Furstner, A.
Angewandte Chemie (International Edition in English), 3012-3012 (2000)
Vougioukalakis, G. C.; Grubbs, R. H.
Chemical Reviews, 1746-1746 (2010)
Grubbs, R. H.
Tetrahedron, 7117-7117 (2004)
Trnka, T. M.; Grubbs, R. H.
Accounts of Chemical Research, 18-18 (2001)
Schuster, M.; Blechert, S.
Angewandte Chemie (International Edition in English), 2036-2036 (1997)
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