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578703

Sigma-Aldrich

Dichloro(3-methyl-2-butenylidene)bis(tricyclopentylphosphine)ruthenium(II)

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About This Item

Empirical Formula (Hill Notation):
C35H62Cl2P2Ru
CAS Number:
220883-08-9
Molecular Weight:
716.79
MDL number:
MFCD04039971
UNSPSC Code:
12352300
PubChem Substance ID:
24880945

form

solid

mp

94-96 °C (lit.)

storage temp.

2-8°C

SMILES string

Cl[Ru]Cl.[CH][CH][C](C)C.C1CCC(C1)P(C2CCCC2)C3CCCC3.C4CCC(C4)P(C5CCCC5)C6CCCC6

InChI

1S/2C15H27P.C5H8.2ClH.Ru/c2*1-2-8-13(7-1)16(14-9-3-4-10-14)15-11-5-6-12-15;1-4-5(2)3;;;/h2*13-15H,1-12H2;1,4H,2-3H3;2*1H;/q;;;;;+2/p-2

InChI key

UCDVULRIJNJVEV-UHFFFAOYSA-L

Application

Metathesis: Ruthenium-Based Metathesis Catalysts

  • Reactant for synthesis of ruthenium olefin metathesis catalysts

  • Catalyst for ring-opening metathesis polymerization
Kinetic application profile similar to that of Grubbs 1st Generation Catalyst.

Other Notes

NO BULK ORDERS

Legal Information

US Patent No. 5,969,170 and foreign equivalents apply. Sale of this product conveys to the buyer a limited-use research license. For questions, please contact us at aldrich@sial.com

pictograms

Flame
GHS02

signalword

Warning

hcodes

H228

pcodes

P210

Hazard Classifications

Flam. Sol. 2

Storage Class

4.1B - Flammable solid hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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Certificates of Analysis (COA)

Lot/Batch Number
01729KH
15315JA

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Furstner, A.
Angewandte Chemie (International Edition in English), 3012-3012 (2000)
Vougioukalakis, G. C.; Grubbs, R. H.
Chemical Reviews, 1746-1746 (2010)
Grubbs, R. H.
Tetrahedron, 7117-7117 (2004)
Schuster, M.; Blechert, S.
Angewandte Chemie (International Edition in English), 2036-2036 (1997)
Trnka, T. M.; Grubbs, R. H.
Accounts of Chemical Research, 18-18 (2001)
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