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234834

Sigma-Aldrich

Cyclopentadienyltitanium(IV) trichloride

97%

Synonym(s):

CpTiCl3

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About This Item

Empirical Formula (Hill Notation):
C5H5Cl3Ti
CAS Number:
1270-98-0
Molecular Weight:
219.32
MDL number:
MFCD00003724
UNSPSC Code:
12161600
PubChem Substance ID:
24854059
NACRES:
NA.22

Assay

97%

form

solid

reaction suitability

core: titanium
reagent type: catalyst

mp

210 °C (dec.) (lit.)

SMILES string

Cl[Ti](Cl)Cl.[CH]1[CH][CH][CH][CH]1

InChI

1S/C5H5.3ClH.Ti/c1-2-4-5-3-1;;;;/h1-5H;3*1H;/q;;;;+3/p-3

InChI key

AENCLWKVWIIOQH-UHFFFAOYSA-K

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Application

Precusor for cyclopentadienyltitanium(IV) complexes, and used as catalysts for alkene polymerizations

Pictograms

Corrosion
GHS05

Signal Word

Danger

Hazard Statements

H314

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Ricci, G.; Italia, S. et al.
The Journal of Organic Chemistry, 451, 67-67 (1993)
McGrane, P. L.; Jensen, M. et al.
Journal of the American Chemical Society, 114, 5459-5459 (1992)
David Hermann Lamparelli et al.
Polymers, 11(4) (2019-04-19)
The direct synthesis of syndiotactic polystyrene-block-polyethylene copolymer (sPS-b-PE) with a diblock structure has been achieved. The synthetic strategy consists of the sequential stereocontrolled polymerization of styrene and ethylene in the presence of a single catalytic system: cyclopentadienyltitanium(IV) trichloride activated by
Erker, G.; Aulbach, M. et al.
Journal of the American Chemical Society, 115, 4590-4590 (1993)
Komal Sethi et al.
Journal of colloid and interface science, 456, 59-65 (2015-06-21)
In this paper, we report the synthesis, characterization of drug-doped organically modified titania nanoparticles, and their applications in sustained drug release. The drug-doped nanoparticles were synthesized in the hydrophobic core of oil-in-water microemulsion medium. Structural aspects obtained through TEM and

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